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Coordination complexes derived from 3,6-di(2-pyridyl)-1,4-dihydro-1,2,4,5-tetrazine (DPDHT). Synthesis and molecular structure of [(DPT)(GaMe2)2]

TitleCoordination complexes derived from 3,6-di(2-pyridyl)-1,4-dihydro-1,2,4,5-tetrazine (DPDHT). Synthesis and molecular structure of [(DPT)(GaMe2)2]
Publication TypeJournal Article
Year of Publication1998
AuthorsPreston, PN, Rettig, SJ, Storr, A, Trotter, J
JournalCanadian Journal of Chemistry-Revue Canadienne De Chimie
Volume76
Pagination1800-1804
Date PublishedDec
Type of ArticleArticle
ISBN Number0008-4042
Keywords3, 5-DIMETHYLPYRAZOLATE, crystal structure, dipyridyldihydrotetrazine, MAGNETIC-PROPERTIES, METAL PYRAZOLATE POLYMERS, METALLOCENES, methylgallium
Abstract

{The facile reaction of 3,6-di(2-pyridyl)-1,4-dihydro-1,2,4,5-tetrazine (DPDHT) (1) with trimethylgallium has resulted in the formation of the purple crystalline product, [(DPT)(GaMe2)(2)] (2), via methane elimination. Crystals of [(DPT)(GaMe2)(2)] are orthorhombic, Pbca

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