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DI-MU-CHLORO-BIS[ETA(5)-CYCLOPENTADIENYL)-NITROSYLMOLYBDENUM]

TitleDI-MU-CHLORO-BIS[ETA(5)-CYCLOPENTADIENYL)-NITROSYLMOLYBDENUM]
Publication TypeJournal Article
Year of Publication1994
AuthorsChristensen, NJ, Legzdins, P, Trotter, J, Yee, VC
JournalActa Crystallographica Section C-Crystal Structure Communications
Volume50
Pagination1558-1559
Date PublishedOct
Type of ArticleArticle
ISBN Number0108-2701
Abstract

The centrosymmetric dimeric molecule of the title compound, [MoCl(NO)(C5H5)]2, contains two Mo(Cp)NO units, where Cp is the cyclopentadienyl ring, with two bridging Cl atoms giving a central four-membered Mo2Cl2 ring. The mean Mo-Cl distance is 2.407 (1) angstrom, with the Mo...Mo’ distance [2.9098 (3) angstrom] in the range for a single metal-metal bond.

URL<Go to ISI>://A1994PN59100014