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Dynamics and energetics of photoion-pair formation in HF/DF

TitleDynamics and energetics of photoion-pair formation in HF/DF
Publication TypeBook Chapter
Year of Publication2005
AuthorsHu, QJ, Hepburn, JW
EditorWolf, A, Lammich, L, Schmelcher, P
Book TitleDR2004: Sixth International Conference on Dissociative Recombination: Theory, Experiments and Applications
Series TitleJournal of Physics Conference Series
Volume4
Pagination267-271
PublisherIop Publishing Ltd
CityBristol
ISBN Number1742-6588
KeywordsDF, DISSOCIATION, F2, HCL, HF, ION, PRODUCTION SPECTROSCOPY, STATES, THRESHOLD
Abstract

Preliminary results of a high resolution coherent vacuum ultraviolet study of photoion-pair formation in HF/DF are reported. These results include threshold ion-pair production (TIPPS) and total photoion-pair yield spectra, which show sharp resonances due to predissociating Rydberg states. Detailed analysis of the spectra provides precise energies for the ion-pair thresholds, and insight into the mechanism for ion-pair formation.

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