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Electron rich bidentate phosphinimine-imine ligands: Synthesis and reactivity of late transition metal complexes.

TitleElectron rich bidentate phosphinimine-imine ligands: Synthesis and reactivity of late transition metal complexes.
Publication TypeJournal Article
Year of Publication2010
AuthorsWallis, CJ, Kraft, IL, Patrick, BO, Mehrkhodavandi, P
JournalDalton Transactions
Volume39
Pagination541 - 547
Date Published2010///
ISBN Number1477-9226
Keywordscrystal structure transition metal phosphinimine imine complex, transition metal phosphinimine imine complex prepn structure
Abstract

{Electron rich phosphinimine-imine proligands Ph3PN(o-C6H4)CPh(:NAr) (LAr) (Ar = 4-(OEt)C6H4 (OEt), 3,5-Me2C6H3 (Xyl)) were synthesized in three steps from 2-aminobenzophenone. These compds., along with previously reported LMes and LTol (Mes = 2,4,6-Me3C6H2