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FACILE NITROSYL N-O BOND-CLEAVAGE UPON THERMOLYSIS OF CP-ASTERISK-W(NO)PH2

TitleFACILE NITROSYL N-O BOND-CLEAVAGE UPON THERMOLYSIS OF CP-ASTERISK-W(NO)PH2
Publication TypeJournal Article
Year of Publication1994
AuthorsBrouwer, EB, Legzdins, P, Rettig, SJ, Ross, KJ
JournalOrganometallics
Volume13
Pagination2088-2091
Date PublishedMay
Type of ArticleNote
ISBN Number0276-7333
KeywordsCHEMISTRY, COMPLEXES, CP’M(NO)R2, MOLYBDENUM, TUNGSTEN
Abstract

{Thermolysis of Cp*W(NO)Ph2 (1) in C6H6 at 60-degrees-C for 24 h affords the new nitrosyl N-0 bond cleavage products Cp*W(eta2-ONPh)(NPh)Ph (2) and [Cp*W(O)Ph](mu-N)[Cp*W(NO)Ph] (3), as well as the known Cp*W(O)2Ph (4), in isolated yields of 10, 9, and 30%, respectively. Complex 2 has been subjected to a single-crystal X-ray crystallographic analysis. Crystals of 2 are orthorhombic, space group Pcab, with a = 16.538(2) angstrom

URL<Go to ISI>://A1994NL71300077