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General synthesis of useful chelating reagents having a sugar unit, 1,3-diamino-2-propyl beta-D-glucopyranoside and 1,3-diamino-2-propyl alpha-D-mannopyranoside

TitleGeneral synthesis of useful chelating reagents having a sugar unit, 1,3-diamino-2-propyl beta-D-glucopyranoside and 1,3-diamino-2-propyl alpha-D-mannopyranoside
Publication TypeJournal Article
Year of Publication1999
AuthorsYano, S, Shinohara, Y, Mogami, K, Yokoyama, M, Tanase, T, Sakakibara, T, Nishida, F, Mochida, K, Kinoshita, I, Doe, M, Ichihara, K, Naruta, Y, Mehrkhodavandi, P, Buglyo, P, Song, B, Orvig, C, Mikata, Y
JournalChemistry Letters
Pagination255-256
Date PublishedMar
Type of ArticleArticle
ISBN Number0366-7022
KeywordsNICKEL(II) COMPLEXES
Abstract

Two 1,3-propanediamine derivatives bearing sugar units, 1,3-diamino-2-propyl beta-D-glucopyranoside (2-beta-D-Glc-pn) and 1,3-diamino-2-propyl alpha-D-mannopyranoside (2-alpha-D-Man-pn), have been prepared and characterized. The structures of two peracetylated diazides, as well as a nickel complex of glucose-type ligand, [Ni(2-beta-D-Glc-pn)(2)SO4] have been determined by X-ray crystallography.

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