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THE MOLECULAR AND ELECTRONIC-STRUCTURE OF 1-PYRAZOLYLPHOSPHAZENES

TitleTHE MOLECULAR AND ELECTRONIC-STRUCTURE OF 1-PYRAZOLYLPHOSPHAZENES
Publication TypeJournal Article
Year of Publication1992
AuthorsGallicano, KD, Paddock, NL, Rettig, SJ, Trotter, J
JournalCanadian Journal of Chemistry-Revue Canadienne De Chimie
Volume70
Pagination1855-1868
Date PublishedJun
Type of ArticleArticle
ISBN Number0008-4042
KeywordsCOMPLEXES, CRYSTAL, CYCLOPHOSPHAZENES, CYCLOTRIPHOSPHAZENE, DIFFRACTION, PHOSPHAZENES, PHOSPHONITRILIC DERIVATIVES, PYRAZOLE, SPECTRA, SUBSTITUENTS
Abstract

{The nature of the interactions between pyrazolyl and phosphazene rings has been investigated through the study of the structures of bis(1-pyrazolyl)methane, CH2(H2pz)2, 1, bis[1-(3,5-dimethylpyrazolyl)]methane, CH2(Me2pz)2, 2, the pyrazolylphosphazenes N3P3(Me2pz)6, 3, N4P4(H2pz)8, 4, and N4P4(Me2pz)8, 5, and the partially substituted gem-N3P3Ph2(Me2pz)4, 6. Crystal data are as follows: 1, orthorhombic, P2(1)2(1)2(1)

URL<Go to ISI>://A1992JR09700038