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NOVEL ROUTE TO THE UNSYMMETRICAL DIALKYL COMPLEX CPW(NO)(CH2SIME3)(CH2CPH3) AND FORMATION OF METALLACYCLES BY THERMOLYSIS OF CPW(NO)(CH2SIME3)(CH2CR2PH) (R=ME, PH)

TitleNOVEL ROUTE TO THE UNSYMMETRICAL DIALKYL COMPLEX CPW(NO)(CH2SIME3)(CH2CPH3) AND FORMATION OF METALLACYCLES BY THERMOLYSIS OF CPW(NO)(CH2SIME3)(CH2CR2PH) (R=ME, PH)
Publication TypeJournal Article
Year of Publication1993
AuthorsBrunet, N, Debad, JD, Legzdins, P, Trotter, J, Veltheer, JE, Yee, VC
JournalOrganometallics
Volume12
Pagination4572-4579
Date PublishedNov
Type of ArticleArticle
ISBN Number0276-7333
KeywordsMO, ORGANOMETALLIC NITROSYL CHEMISTRY, TUNGSTEN
Abstract

{Treatment of CpW(NO)(CH2SiMe3)2 (CP =eta5-C5H5) with [Ph3C]PF6 results in cleavage of the Si-C bond and formation of the unsymmetrical dialkyl complex CpW(NO) (CH2SiMe3)(CH2CPh3) (1). Crystal data for 1: a = 10.930(2) angstrom

URL<Go to ISI>://A1993MH64500048