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ORGANOMETALLIC NITROSYL CHEMISTRY .53. SYNTHESIS, CHARACTERIZATION, AND PROPERTIES OF 16-ELECTRON CP-ASTERISK-M(NO)(ARYL)2 (M = MO, W) COMPLEXES

TitleORGANOMETALLIC NITROSYL CHEMISTRY .53. SYNTHESIS, CHARACTERIZATION, AND PROPERTIES OF 16-ELECTRON CP-ASTERISK-M(NO)(ARYL)2 (M = MO, W) COMPLEXES
Publication TypeJournal Article
Year of Publication1992
AuthorsDryden, NH, Legzdins, P, Rettig, SJ, Veltheer, JE
JournalOrganometallics
Volume11
Pagination2583-2590
Date PublishedJul
Type of ArticleArticle
ISBN Number0276-7333
KeywordsMOLYBDENUM, TUNGSTEN
Abstract

{Treatment of Cp*M(NO)Cl2 (Cp* = eta-5-C5Me5; M = Mo, W) in THF at low temperatures with equimolar amounts of diarylmagnesium reagents, (aryl)2Mg.x(dioxane), affords the diaryl complexes Cp*M(NO)(aryl)2 (aryl = Ph, o-tolyl, or p-tolyl), which are isolable in moderate yields and have been fully characterized by conventional spectroscopic methods. In addition, single-crystal X-ray crystallographic analyses have been performed on both o-tolyl complexes. Crystal data for Cp*Mo(NO)(o-tolyl)2 (3): a = 11.570 (2) angstrom

URL<Go to ISI>://A1992JD62200048