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REACTIONS OF 16-ELECTRON CP’M(NO)R2 COMPOUNDS [M = MO, W R = ALKYL, ARYL] WITH CARBON-MONOXIDE

TitleREACTIONS OF 16-ELECTRON CP’M(NO)R2 COMPOUNDS [M = MO, W R = ALKYL, ARYL] WITH CARBON-MONOXIDE
Publication TypeJournal Article
Year of Publication1993
AuthorsDryden, NH, Legzdins, P, Lundmark, PJ, Riesen, A, Einstein, FWB
JournalOrganometallics
Volume12
Pagination2085-2093
Date PublishedJun
Type of ArticleArticle
ISBN Number0276-7333
KeywordsCOORDINATION, CRYSTAL, ETA-2-ACYL COMPLEXES, MOLYBDENUM, ORGANOMETALLIC NITROSYL CHEMISTRY, TUNGSTEN
Abstract

{This paper reports the reactions of 16-electron Cp’M(NO)R2 complexes [Cp’ = CP (eta5-C5H5), Cp* (eta5-C5Me5); M = Mo, W; R = alkyl, aryl] with carbon monoxide. The reactions proceed in a stepwise fashion, and their outcomes are dependent on both the natures of Cp’ and R and the experimental conditions employed. Thus, treatment of solutions of Cp’W(NO)R2 with CO under ambient conditions affords the corresponding 18-electron monoacyl species Cp’W(NO)-(eta2-C{O}R) (R) (Cp’ = Cp*

URL<Go to ISI>://A1993LG15800019