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{The reactions of the third transition series metal hexafluorides, MF6

Title{The reactions of the third transition series metal hexafluorides, MF6
Publication TypeJournal Article
Year of Publication2000
Authorsvon Ahsen, B, Bach, C, Pernice, H, Willner, H, Aubke, F
JournalJournal of Fluorine Chemistry
Volume102
Pagination243-252
Date PublishedMar
Type of ArticleArticle
ISBN Number0022-1139
Keywords<IR(CO)(6)>(3+), carbonyl fluoride, CO, FLUOROSULFATES, HEXACARBONYLS, homoleptic carbonyl complexes, INCLUDING STEREOISOMERS, metal hexafluorides, MOLECULAR-STRUCTURE, NOBLE-METALS, PALLADIUM(II), platinum, superacid, UNDECAFLUORODIANTIMONATE(V), VIBRATIONAL-SPECTRA
Abstract

{The reactions of the third transition (5d) series metal hexafluorides PtF6, IrF6, OsF6, ReF6 and WF6 with CO are studied in the Lewis superacid SbF5, the Bronsted superacid HF and the conjugate Bronsted-Lewis superacid HF-SbF5, in order to evaluate their potential as reactants in reductive carbonylations. These reactions are aimed at the generation of homoleptic metal carbonyl cations of the type [M(CO)(n)](m+)

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