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Scandium-catalyzed intramolecular hydroamination. Development of a highly active cationic catalyst

TitleScandium-catalyzed intramolecular hydroamination. Development of a highly active cationic catalyst
Publication TypeJournal Article
Year of Publication2004
AuthorsLauterwasser, F, Hayes, PG, Brase, S, Piers, WE, Schafer, LL
JournalOrganometallics
Volume23
Pagination2234-2237
Date PublishedMay
Type of ArticleArticle
ISBN Number0276-7333
KeywordsALKENES, ALKYNES, AMIDO COMPLEXES, BETA-DIKETIMINATO LIGANDS, DERIVATIVES, GROUP-3 METALS, ORGANOSCANDIUM, REACTIVITY, YTTRIUM, ZIRCONIUM
Abstract

The scandium-catalyzed intramolecular hydroamination of alkynes and alkenes is reported. Complex structure/catalyst activity investigations resulted in the identification of a highly catalytically active cationic, beta-diketiminato scandium complex.
URL<Go to ISI>://000221231100006