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STRUCTURAL STUDIES OF ORGANOBORON COMPOUNDS .50. 4-(2-HYDROXY-2,2-DIPHENYLACETYL)-6,6-PENTAMETHYLENE-2-PHENYL-1,3-DIOXA-4 -AZA-2-BORACYCLOHEXANE AND 4-[2,2-DIFLUORO-5,5-BIS(4-METHOXYPHENYL)-1,3-DIOXA-2-BORATA-4-CYCLOPENTY LIDENE]-6,6-PENTAMETHYLENE-2-PHEN

TitleSTRUCTURAL STUDIES OF ORGANOBORON COMPOUNDS .50. 4-(2-HYDROXY-2,2-DIPHENYLACETYL)-6,6-PENTAMETHYLENE-2-PHENYL-1,3-DIOXA-4 -AZA-2-BORACYCLOHEXANE AND 4-[2,2-DIFLUORO-5,5-BIS(4-METHOXYPHENYL)-1,3-DIOXA-2-BORATA-4-CYCLOPENTY LIDENE]-6,6-PENTAMETHYLENE-2-PHEN
Publication TypeJournal Article
Year of Publication1992
AuthorsKliegel, W, Preu, L, Schumacher, U, Rettig, SJ, Trotter, J
JournalCanadian Journal of Chemistry-Revue Canadienne De Chimie
Volume70
Pagination1176-1187
Date PublishedApr
Type of ArticleArticle
ISBN Number0008-4042
KeywordsADJACENT ACYL LIGANDS, CARBON BOND FORMATION, COORDINATED MOLECULES, CRYSTAL, HYDROXAMIC ACIDS, LENGTHS, RING
Abstract

{The preparation of the organoboron compounds 4-(2-hydroxy-2,2-diphenylacetyl)-6,6-pentamethylene-2-phenyl-1,3-dioxa-4 -aza-2-boracyclohexane, 6, 4-(2,2-difluoro-5,5-diphenyl-1,3-dioxa-2-borata-4-cyclopentylidene)-6,6- pentamethylene-2-phenyl-1,3,-dioxa-4-azonia-2-boracyclohexane, 14a, and 4-[2,2-difluoro-5,5-bis(4-methoxyphenyl)-1,3-dioxa-2-borata-4-cyclopenty lidene]-6,6-pentamethylene-2-phenyl-1,3-dioxa-4-azonia-2-boracyclohexane , 14b, are reported. Crystals of 6 are triclinic, P1BAR

URL<Go to ISI>://A1992JH89500021