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Synthesis and structural studies of chiral indium(III) complexes supported by tridentate diaminophenol ligands.

TitleSynthesis and structural studies of chiral indium(III) complexes supported by tridentate diaminophenol ligands.
Publication TypeJournal Article
Year of Publication2010
AuthorsAcosta-Ramirez, A, Douglas, AF, Yu, I, Patrick, BO, Diaconescu, PL, Mehrkhodavandi, P
JournalInorganic Chemistry (Washington, DC, United States)
Volume49
Pagination5444 - 5452
Date Published2010///
ISBN Number0020-1669
Keywordscrystal structure dimethylindium dihaloindium cyclohexanediamine phenolate tridentate complex, hydrolysis binuclear indium cyclohexanediamine phenolate tridentate complex, indium organometallic cyclohexanediamine phenol tridentate complex prepn structure, mol structure dimethylindium dihaloindium cyclohexanediamine phenolate tridentate complex, protonolysis substitution prepn dimethylindium dihaloindium cyclohexanediamine phenolate tridentate complex
Abstract

{Indium trans-cyclohexanediamine-phenol tridentate di-Me, dihalide, and alkoxy-bridged complexes were prepd. and characterized. Protonolysis of InMe3 with the phenolic group of the ligand, trans-2-(Me2N)C6H10NHCH2C6H2-3,5-tBu2-2-OH (H-NNO) gave pentacoordinate indium complexes [(NNO)InMe2] (1) and [Me2ClIn(μ-NNO)InMe2] (2) with meridional NNO-frame. Substitution of potassium phenolate K(NNO) with InX3 gave dihalides [(NNO)InX2] (3-5