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SYNTHESIS, CHARACTERIZATION, AND REACTIVITY OF ALKOXO COMPLEXES CONTAINING CP-ASTERISK-M(NO) GROUPS (M=MO, W)

TitleSYNTHESIS, CHARACTERIZATION, AND REACTIVITY OF ALKOXO COMPLEXES CONTAINING CP-ASTERISK-M(NO) GROUPS (M=MO, W)
Publication TypeJournal Article
Year of Publication1993
AuthorsLegzdins, P, Lundmark, PJ, Rettig, SJ
JournalOrganometallics
Volume12
Pagination3545-3552
Date PublishedSep
Type of ArticleArticle
ISBN Number0276-7333
KeywordsALKYL, MOLYBDENUM, ORGANOMETALLIC NITROSYL CHEMISTRY, PI-DONATION, TUNGSTEN
Abstract

{Stepwise treatment of Cp*M(NO)Cl2 [CP* = eta5-C5Me5;M = Mo,W] in THF at low temperatures with 2 equiv of alkoxide anion affords first Cp*M(NO)(OR)CI complexes and then the bis(alkoxo) compounds Cp*M(NO)(OR)2 [M = Mo

URL<Go to ISI>://A1993LX17200029