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THERMAL CHEMISTRY OF CPMO(NO)(CH2CME3)2 - LEWIS BASE ADDUCTS OF CPMO(NO)(=CHCME3) AND A NEW BONDING MODE FOR NITRIC-OXIDE

TitleTHERMAL CHEMISTRY OF CPMO(NO)(CH2CME3)2 - LEWIS BASE ADDUCTS OF CPMO(NO)(=CHCME3) AND A NEW BONDING MODE FOR NITRIC-OXIDE
Publication TypeJournal Article
Year of Publication1993
AuthorsLegzdins, P, Rettig, SJ, Veltheer, JE, Batchelor, RJ, Einstein, FWB
JournalOrganometallics
Volume12
Pagination3575-3585
Date PublishedSep
Type of ArticleArticle
ISBN Number0276-7333
KeywordsMETAL MULTIPLE BONDS, METATHESIS, MOLYBDENUM, NEOPENTYLIDENE COMPLEXES, ORGANOMETALLIC NITROSYL CHEMISTRY, {LIGANDS
Abstract

{Treatment of CpMo(NO)Cl2 with (Me3CCX2)2Mg-X(dioxane) [X = H, D] in THF at low temperatures provides moderate yields of the bis(neopentyl) complexes, CpMo(NO)(CH2CMe3)2 (1) and CpMo(NO)(CD2CMe3)2 (1-d4). The solid-state molecular structure of 1-d4 has been determined at 170 K. Crystals of 1-d4 are monoclinic of space group P2(1)/n; a = 5.9781(6) angstrom

URL<Go to ISI>://A1993LX17200033