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THERMOLYSIS OF RU3(CO)10[FE(ETA-C5H4PPRI2)2] - STRUCTURE OF RU3(CO)8(MU-H)2[ETA-PC5H4)FE(ETA-C5H4PPRI2)] AND RU3(CO)8(MU-H)(MU-OH)[MU-FE(ETA-C5H4PPRI2)2]

TitleTHERMOLYSIS OF RU3(CO)10[FE(ETA-C5H4PPRI2)2] - STRUCTURE OF RU3(CO)8(MU-H)2[ETA-PC5H4)FE(ETA-C5H4PPRI2)] AND RU3(CO)8(MU-H)(MU-OH)[MU-FE(ETA-C5H4PPRI2)2]
Publication TypeJournal Article
Year of Publication1992
AuthorsCullen, WR, Rettig, SJ, Zheng, TC
JournalOrganometallics
Volume11
Pagination853-858
Date PublishedFeb
Type of ArticleArticle
ISBN Number0276-7333
KeywordsBENZYNE COMPLEXES, CLUSTER CHEMISTRY, COORDINATION, MOLECULAR-STRUCTURE, OSMIUM, RAY CRYSTAL-STRUCTURE, SURFACE, X-RAY
Abstract

{Heating Ru3(CO)10(Fc’(PPr(i)2)2) (Fc’ = Fe(eta-C5H4)2) in refluxing cyclohexane affords three products in moderate yields. The complex Ru3(CO)8(mu-H)2[(eta-PC5H4)Fe(eta-C5H4PPr(i)2)] (7) was characterized by X-ray diffraction. It crystallizes in the triclinic system, space group P1BAR, with a = 11.782 (4) angstrom

URL<Go to ISI>://A1992HE29800052