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A TUNGSTEN NITROSYL COMPLEX

TitleA TUNGSTEN NITROSYL COMPLEX
Publication TypeJournal Article
Year of Publication1995
AuthorsEvans, SV, Legzdins, P, Rettig, SJ, Sanchez, L, Trotter, J
JournalActa Crystallographica Section C-Crystal Structure Communications
Volume51
Pagination584-586
Date PublishedApr
Type of ArticleArticle
ISBN Number0108-2701
Abstract

{Insertion of nitric oxide into one W-C bond a bis(trimethylsilyl)tungsten complex results in formation of a bidentate N-trimethylsilylmethyl-N-nitrosohydroxylaminato ligand. The resulting complex, (eta(5)-cyclopentadienyl)nitrosyl(trimethylsilyl- methyl)(N-trimethylsilylmethyl-N-nitrosohydroxylaminato)tungsten, [W(NO)(C5H5)(C4H11N2O2Si)(C4H11Si)], crystallizes in space group P $($) over bar$$ 1

URL<Go to ISI>://A1995QZ66200018