@article {4998,
	title = {Organometallic oxides: Oxidation of the cubane [(eta-C5R5)Cr(mu(3)-O)](4) and the structures and magnetic properties of the salts {[(eta-C5R5)Cr(mu(3)-O)](4)}{tcnq} and {[(eta-C5R5)Cr(mu(3)-O)](4)}{BF4},
	journal = {Organometallics},
	volume = {20},
	number = {9},
	year = {2001},
	note = {ISI Document Delivery No.: 428DKTimes Cited: 5Cited Reference Count: 41},
	month = {Apr},
	pages = {1840-1848},
	type = {Article},
	abstract = {Differential pulse and current voltammetry for the cubane-like clusters [(eta -C5R5)Cr(mu (3)-O)](4) (R = H, Me; R-5 = H4Me) showed that [(eta -C5H4Me)Cr(mu (3)-O)](4) and [(eta -C5Me5)Cr(mu (3)-O)](4) were oxidized to {[(eta -C5R5)Cr(mu (3)-O)](4)}(+) and then to {[(eta -C5R5)Cr(mu (3)-O)](4)}(2+), but [(eta -C5H5)-Cr(mu (3)-O)](4) was oxidized only to {[(eta -C5H5)Cr(mu (3)-O)](4)}(+). Oxidation of [(eta -C5Me5)Cr(mu (3)-O)](4) (1) by AgBF4 or tcnq gave {[(eta -C5Me5)Cr(mu (3)-O)](4)}{BF4} (2) {[(eta -C5Me5)Cr(mu (3)-O)](4)}{tcnq} (3). It was shown by X-ray diffraction that the average Cr-Cr, Cr-O, and Cr-Cp* distances in 2 and 3 were 0.034(2), 0.007(5), and 0.02(1) Angstrom shorter than those in 1, respectively. Compounds 1 2, and 3 were antiferromagnetic., with similar intracluster exchange coupling constants, J (-262(23), -211(34), and -266(46) cm(-1), respectively). There was coupling between unpaired electrons on {[(eta -C5Me5)Cr(mu (3)-O)](4)}(+) and {tcnq}(-) in 3 at temperatures below 110 Ii.},
	keywords = {<(ETA-C5H5)CR(MU-3-O)>4, CLUSTERS, COMPLEXES, CRYSTAL-STRUCTURES, MONONUCLEAR, REACTIVITY, SINGLE-MOLECULE MAGNETS, TCNQ, X-ray structure},
	isbn = {0276-7333},
	url = {<Go to ISI>://000168445800017},
	author = {Allen, D. P. and Bottomley, F. and Day, R. W. and Decken, A. and Sanchez, V. and Summers, D. A. and Thompson, R. C.}
}
