@article {3870,
	title = {Organometallic halides: Preparation and physical and chemical properties of tris[(eta-pentamethylcyclopentadienyl)dichlorovanadium], [(eta-C5Me5)V(mu-Cl)(2)](3)},
	journal = {Organometallics},
	volume = {16},
	number = {9},
	year = {1997},
	note = {ISI Document Delivery No.: WX030Times Cited: 14Cited Reference Count: 60},
	month = {Apr},
	pages = {1865-1869},
	type = {Article},
	abstract = {The cluster [(eta-C5Me5)V(mu-Cl)(2)](3) was synthesized from VCl3(thf)(3) and (Bu3SnC5Me5)-Sn-n. It was oxidized by O-2 to give (eta-C5Me5)VCl2(O), and by NaN3 to give [(eta-C5Me5)VCl(mu-N)](2). X-ray diffraction showed that [(eta-C5Me5)V(mu-Cl)(2)](3) had an equilateral triangle of vanadium atoms (mean V-V 3.367 (2) Angstrom), with each edge of the triangle symmetrically bridged by two chlorine atoms. The cluster contains six core electrons. The cluster [(eta-C5Me5)V(mu-Cl-2](3) had a magnetic moment of 2.92 mu(B) at room temperature and showed antiferromagnetic behavior.},
	keywords = {CHROMIUM(III), CRYSTAL-STRUCTURE, DERIVATIVES, HALF-SANDWICH COMPLEXES, MAIN-GROUP ELEMENTS, multiple bonds, OXIDES, OXO, TRANSITION-METALS, {ALKYLS},
	isbn = {0276-7333},
	url = {<Go to ISI>://A1997WX03000011},
	author = {Abernethy, C. D. and Bottomley, F. and Decken, A. and Thompson, R. C.}
}
