@article {4740, title = {The synthesis and the molecular structure of hexakis (carbonyl)hexafluoroantimonato(V)tungsten(II) undecafluorodiantimonate (V), [W(CO)(6)(FSbF5)][Sb2F11]}, journal = {Inorganic Chemistry}, volume = {39}, number = {10}, year = {2000}, note = {ISI Document Delivery No.: 315QGTimes Cited: 10Cited Reference Count: 35}, month = {May}, pages = {2172-2177}, type = {Article}, abstract = {{The reaction of tungsten hexacarbonyl, W(CO)(6), with antimony(V) fluoride, SbF5, in the conjugate Bronsted-Lewis superacid HF-SbF5 at 40 degrees C produces quantitatively the salt [W(CO)(6)(FSbF5)][Sb2F11] as the main product. The observed 2e(-) oxidation without any loss of CO is unprecedented. The cation [W(CO)(6)(FSbF5)](+) is seven coordinated with a distorted C-2v capped trigonal prismatic structure. [W(CO)(6)(FSbF5)][Sb2F11] crystallizes in the monoclinic space group P-21 (No. 4). a 8.2051(12) Angstrom}, keywords = {ANIONS, COMPLEXES, COORDINATION, CRYSTAL-STRUCTURE}, isbn = {0020-1669}, url = {://000087124000027}, author = {Brochler, R. and Sham, I. H. T. and Bodenbinder, M. and Schmitz, V. and Rettig, S. J. and Trotter, J. and Willner, H. and Aubke, F.} }