@article {3925,
	title = {Selectivity among, and aggregation of, lanthanide ions},
	journal = {Journal of Alloys and Compounds},
	volume = {249},
	number = {1-2},
	year = {1997},
	note = {ISI Document Delivery No.: XC092Times Cited: 4Cited Reference Count: 1421st Rare Earth Research ConferenceJUL 07-12, 1996DULUTH, MNRare Earth Res Conf Inc, Univ Minnesota, USR Optonix Inc, Amer Chem Soc, Petr Res Fund, Arris Int Corp, Baotou Steel \& Rare Earth Co, US},
	month = {Mar},
	pages = {49-51},
	type = {Proceedings Paper},
	abstract = {Ligands that show selectivity towards, and aggregation of, lanthanides are of intrinsic interest in coordination chemistry. We have shown that Schiff base and amine phenolate ligands exhibit a variety of coordination modes in lanthanide(III) complexes, and that tren-(tris((2-amino)ethyl)amine)-based amine phenolates show selectivity towards later lanthanide(III) ions. By altering the nature of the amine phenolate ligand backbone the coordination mode of the ligand in solution can be easily controlled. Selectivity among lanthanide(III) ions can be controlled by substitution of the parent ligand donor atoms (phenolate oxygen) with donor atoms of a different type (e.g. phosphinate oxygen). By derivatizing the ligand to include more donor atoms and by stiffening the backbone, it is possible to control the aggregation of lanthanide(III) ions (enabling the formation of dimeric lanthanide complexes).},
	keywords = {aggregation of lanthanide ions, AMINE PHENOL LIGANDS, COMPLEXES, DESIGN, HEPTADENTATE LIGANDS, METAL-IONS, selectivity among lanthanide ions},
	isbn = {0925-8388},
	url = {<Go to ISI>://A1997XC09200010},
	author = {Caravan, P. and Lowe, M. P. and Read, P. W. and Rettig, S. J. and Yang, L. W. and Orvig, Chris}
}
