@article { ISI:000334013100015, title = {Phosphodiesters serve as potentially tunable aglycones for fluoro sugar inactivators of retaining beta-glycosidases}, journal = {ORGANIC \& BIOMOLECULAR CHEMISTRY}, volume = {12}, number = {16}, year = {2014}, month = {APR 28}, pages = {2592-2595}, abstract = {2-Deoxy-2-fluoroglycosides bearing dibenzyl phosphate and phosphonate aglycones were synthesised and tested as covalent inactivators of several retaining alpha- and beta-glycosidases. beta-D-Gluco-, -manno- and -galacto-configured benzyl-benzylphosphonate derivatives efficiently inactivated beta-gluco-, beta-manno- and beta-galactosidases, while alpha-gluco- and alpha-manno-configured phosphate and phosphonate derivatives served instead as slow substrates.}, issn = {1477-0520}, doi = {10.1039/c4ob00235k}, author = {Rempel, B. P. and Withers, S. G.} }