@article { ISI:000289505500018, title = {High-resolution calorimetry on thermal behavior of glycerol (I): Glass transition, crystallization and melting, and discovery of a solid-solid transition}, journal = {CHEMICAL PHYSICS LETTERS}, volume = {506}, number = {4-6}, year = {2011}, month = {APR 20}, pages = {217-220}, abstract = {We determined temperature scanning thermograms of glycerol, with the same scanning rate for cooling and warming cycles by using an ultra-sensitive calorimeter at the scanning rate beta from 0.05 to 4 mK/s. Four peaks were observed during the warming process starting from below the glass transition temperature T{\textquoteright}(g); glass transition, crystallization, solid-solid phase transition, and melting. T{\textquoteright}(g) and the crystallization temperature T(p) depends on beta with Arrhenius relation. A broad melting behavior was obtained in a temperature range larger than 10 K, which suggests that structural distribution exists in the crystal. The solid-solid phase transition at 229.1 K was discovered. (c) 2011 Elsevier B.V. All rights reserved.}, issn = {0009-2614}, doi = {10.1016/j.cplett.2011.03.043}, author = {Sou, Kalyan and Nishikawa, Keiko and Koga, Yoshikata and Tozaki, Ken-ichi} }