@article { ISI:000088759200012,
	title = {Synthesis and reactivity of ruthenium(II) complexes containing hemilabile phosphine-thiophene ligands},
	journal = {JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS},
	number = {16},
	year = {2000},
	pages = {2729-2737},
	abstract = {The syntheses of two new phosphine-thiophene ligands, 2-(2{\textquoteright}-\{diphenylphosphino\}phenyl)thiophene (dpppth) and 3{\textquoteright}-diphenylphosphino-2,2{\textquoteright}:5{\textquoteright},2 {\textquoteleft}{\textquoteleft}-terthiophene (dppterth) are reported. These ligands react with {[}RuCl2(PPh3)(3)] to give {[}RuCl2(dpppth-P,S)(2)] and {[}RuCl2(dppterth-P,S-1)(2)], respectively, which both exist as a mixture of two isomers in solution. {[}RuCl2(dpppth-P,S)(2)] reacts at 25 degrees C with carbon monoxide to yield a mixture of {[}RuCl2(CO)(dpppth-P)(dpppth-P,S)] and {[}RuCl2(CO)(2)(dpppth-P)(2)], while {[}RuCl2(dppterth-P,S-1)(2)] reacts with CO under the same conditions to give only the monocarbonyl complex {[}RuCl2(CO)(dppterth-P)(dppterth-P,S-1)]. Displacement of one of the dppterth ligands in {[}RuCl2(dppterth-P,S-1)(2)] with bis(diphenylphosphino)methane (dppm) yields cis-{[}RuCl2(dppm)(dppterth-P,S-1)] which isomerizes in solution to trans-{[}RuCl2(dppm)(dppterth-P,S-1)]. These complexes react with carbon monoxide to give trans-{[}RuCl2(CO)(dppm)(dppterth-P)] and cis-{[}RuCl2(CO)(dppm)(dppterth-P)], respectively, in which the thiophene end of the dppterth ligand is displaced by CO. The electronic spectra of these complexes are reported. Crystal structures for {[}RuCl2(dpppth-P,S)(2)], {[}RuCl2(CO)(dppterth-P)(dppterth-P,S-1)] and cis-{[}RuCl2(dppterth-P,S-1)(dppm)] are reported.},
	issn = {1470-479X},
	doi = {10.1039/b001898h},
	author = {Clot, O and Wolf, MO and Yap, GPA and Patrick, BO}
}
