@article {doi:10.1021/jacs.6b05143,
	title = {Toward anti-Markovnikov 1-Alkyne O-Phosphoramidation: Exploiting Metal{\textendash}Ligand Cooperativity in a 1,3-N,O-Chelated Cp*Ir(III) Complex},
	journal = {Journal of the American Chemical Society},
	volume = {138},
	number = {27},
	year = {2016},
	note = {PMID: 27327491},
	pages = {8396-8399},
	abstract = {Metal{\textendash}ligand cooperation between iridium(III) and a 1,3-N,O-chelating phosphoramidate ligand has been used to develop a protocol for the intermolecular O-phosphoramidation of 1-alkynes. This selective C{\textendash}O bond-forming reaction differs from that of standard amidation reactions, highlighting the ability to control N- or O-functionalization based on judicious choice of N,O-chelating ligand and metal center. Advances toward the development of catalytic anti-Markovnikov O-phosphoramidation using iridium(III), including characterization of rare reactive intermediates that invoke 1,3-bidentate donor ligand hemilability, are disclosed.},
	doi = {10.1021/jacs.6b05143},
	url = {http://dx.doi.org/10.1021/jacs.6b05143},
	author = {Marcus W. Drover and Jennifer A. Love and Laurel L. Schafer}
}
