@article { ISI:000403683400001,
	title = {C(sp(3))-H Bond Activation Induced by Monohydroborane Coordination at an Iridium(III)-Phosphoramidate Complex},
	journal = {EUROPEAN JOURNAL OF INORGANIC CHEMISTRY},
	number = {20},
	year = {2017},
	month = {MAY 26},
	pages = {2639-2642},
	abstract = {The reaction of Cp{*}Ir-III phosphoramidate (Cp{*} = pentamethylcyclopentadienyl) complexes with a monohydroborane (HBR2; R = cyclohexyl or mesityl) generates cyclometalated Cp{*}Ir-III complexes following two sequential intramolecular B-H and C(sp(3))-H bond-activation events. Preliminary mechanistic inquiry suggests that boron stabilization provided by the hemilabile phosphoramidate ligand provides a delta-B-H center dot center dot center dot{[}Ir] coordinated intermediate, which succumbs to borane-induced C(sp(3))-H bond activation.},
	issn = {1434-1948},
	doi = {10.1002/ejic.201601518},
	author = {Drover, Marcus W. and Christopherson, Cheyenne J. and Schafer, Laurel L. and Love, Jennifer A.}
}
