@article {32775,
	title = {Iron Porphyrins Embedded into a Supramolecular Porous Organic Cage for Electrochemical CO2 Reduction in Water},
	journal = {Angewandte Chemie International Edition},
	volume = {57},
	year = {2018},
	pages = {9684-9688},
	abstract = {<p>Abstract A porous organic cage composed of six iron tetraphenylporphyrins was used as a supramolecular catalyst for electrochemical CO2-to-CO conversion. This strategy enhances active site exposure and substrate diffusion relative to the monomeric catalyst, resulting in CO generation with near-quantitative Faradaic efficiency in pH 7.3 water, with activities reaching 55\&thinsp;250 turnovers. These results provide a starting point for the design of supramolecular catalysts that can exploit the properties of the surrounding matrix yet retain the tunability of the original molecular unit.</p>},
	keywords = {CO2 reduction, ELECTROCHEMISTRY, porous organic cages, porphyrins, supramolecular chemistry},
	doi = {10.1002/anie.201803873},
	url = {https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201803873},
	author = {Smith, Peter T. and Benke, Bahiru Punja and Cao, Zhi and Kim, Younghoon and Nichols, Eva M. and Kim, Kimoon and Chang, Christopher J.}
}
