@article {MORGAN2022153688,
	title = {Dentigerumycin F and G: Dynamic structures retrieved through a genome-mining/nitrogen-NMR methodology},
	journal = {Tetrahedron Letters},
	volume = {94},
	year = {2022},
	pages = {153688},
	abstract = {Continual efforts to unearth new natural product chemistry expands our understanding of the scope of chemical space. Here we report the two low-abundance piperazic acid-containing linear peptides dentigerumycins F (1) and G (2), discovered through a combined genome-mining/15N NMR-based discovery method. Dentigerumycins F and G demonstrate a dynamic equilibrium in their oxane ring systems, which complicated structure elucidation. The application of various NMR solvents and conditions revealed the constitution of these natural products.},
	keywords = {Genome mining, Natural product discovery, Nitrogen-15, NMR-guided discovery, Piperazic acid},
	issn = {0040-4039},
	doi = {https://doi.org/10.1016/j.tetlet.2022.153688},
	url = {https://www.sciencedirect.com/science/article/pii/S0040403922000739},
	author = {Kalindi D. Morgan and David E. Williams and Katherine S. Ryan and Raymond J. Andersen}
}
