@article {3610,
	title = {Synthesis and spectroscopic characterization of bis(trifluorophosphinyl)-gold(I) undecafluorodiantimonate(V) [Au(PF3)(2)][Sb2F11]},
	journal = {Canadian Journal of Chemistry-Revue Canadienne De Chimie},
	volume = {74},
	number = {11},
	year = {1996},
	note = {ISI Document Delivery No.: WC124Times Cited: 3Cited Reference Count: 20},
	month = {Nov},
	pages = {2392-2394},
	type = {Article},
	abstract = {The synthesis of [Au(PF3)(2)][Sb2F11], the first trample of a linear, thermally stable metal bis(trifluorophosphine) complex is achieved by CO substitution of [Au(CO)(2)][Sb2F11] by PF3. The [A(PF3)(2)](+) cation can also be generated by reductive phosphorylation by an excess of PF3 in fluorosulfuric acid. Spectroscopic characterization involves F-19 and P-31 NMR in HSO3F and SO2 solution including spectral simulation by the WIN-DAISY method and FT-IR and Raman spectra. Spectroscopic evidence suggests that the metal-ligand bond involves predominantly sigma-bonding with drastically reduced pi-back-donation.},
	keywords = {CHEMISTRY, F-19 NMR, gold(I) complex, gold(I) PF3 complex, linear, P-31 NMR, SPECTRA, vibrational spectra},
	isbn = {0008-4042},
	url = {<Go to ISI>://A1996WC12400054},
	author = {Bley, B. and Bodenbinder, M. and Balzer, G. and Willner, H. and Hagele, G. and Mistry, F. and Aubke, F.}
}
