@article {3541, title = {NEW HOMOLEPTIC METAL-CARBONYL CATIONS - THE SYNTHESES, VIBRATIONAL AND C-13 MAS NMR-SPECTRA OF HEXACARBONYL-RUTHENIUM(II) AND HEXACARBONYL-OSMIUM(II) UNDECAFLUORODIANTIMONATE(V), [RU(CO)(6)][SB2F11](2) AND [OS(CO)(6)][SB2F11](2)}, journal = {Journal of the Chemical Society-Chemical Communications}, number = {20}, year = {1995}, note = {ISI Document Delivery No.: TB415Times Cited: 38Cited Reference Count: 22}, month = {Oct}, pages = {2071-2072}, type = {Article}, abstract = {The new homoleptic carbonyl cations [Ru(CO)(6)](2+) and [Os(CO)(6)](2+) are obtained as [Sb2F11](-) salts by the reductive carbonylation of M(SO3F)(3) (M = Ru, Os), under very mild conditions (60-90 degrees C, 1 atm CO), in liquid SbF5 in a simple, one-step procedure, and are characterized by FT Raman, FTIR and C-13 MAS NMR spectroscopy.}, keywords = {FLUOROSULFATES, NOBLE-METALS}, isbn = {0022-4936}, url = {://A1995TB41500013}, author = {Wang, C. Q. and Bley, B. and Balzerjollenbeck, G. and Lewis, A. R. and Siu, S. C. and Willner, H. and Aubke, F.} }