@article {3581, title = {ANTIMONY(III) FLUORIDE FLUOROSULFATES - SYNTHESES AND MOLECULAR-STRUCTURES OF ANTIMONY(III) DIFLUORIDE FLUOROSULFATE [SBF2(SO3F)](X), ANTIMONY(III) FLUORIDE BIS(FLUOROSULFATE) [SBF(SO3F)(2)](X), AND ANTIMONY(III) TRIS(FLUOROSULFATE) [SB(SO3F)(3)](X)}, journal = {Inorganic Chemistry}, volume = {34}, number = {12}, year = {1995}, note = {ISI Document Delivery No.: RC424Times Cited: 7Cited Reference Count: 52}, month = {Jun}, pages = {3153-3164}, type = {Article}, abstract = {{Following unsuccessful attempts to confirm the existence of previously reported antimony(I) fluorosulfate, Sb(SO3F), the reaction of antimony and fluorosulfuric acid is reinvestigated and synthetic routes are developed that allow the preparation of polymeric [SbF2(SO3F)](x), [SbF(SO3F)(2)](x), and [Sb(SO3F)(3)](x). Recrystallization from fluorosulfuric acid is found to produce single crystals of all three materials, which are suitable for molecular structure determinations by single-crystal X-ray diffraction. Crystals of [SbF2(SO3F)](x) are orthorhombic}, keywords = {CRYSTAL-STRUCTURE, DERIVATIVES, MOSSBAUER, SPECTRA}, isbn = {0020-1669}, url = {://A1995RC42400005}, author = {Zhang, D. L. and Rettig, S. J. and Trotter, J. and Aubke, F.} }