@article {3064,
	title = {THE SYNTHESES AND VIBRATIONAL-SPECTRA OF BIS(CARBONYL)PLATINUM(II) FLUOROSULFATE, PT(CO)2(SO3F)2, AND BIS(CARBONYL)PALLADIUM(II) FLUOROSULFATE, PD(CO)2(SO3F)2},
	journal = {Journal of Fluorine Chemistry},
	volume = {66},
	number = {2},
	year = {1994},
	note = {ISI Document Delivery No.: MX367Times Cited: 26Cited Reference Count: 43},
	month = {Feb},
	pages = {159-166},
	type = {Article},
	abstract = {Reductive carbonylation of platinum(IV) tetrakis(fluorosulfate), Pt(SO3F)4, in fluorosulfuric acid at 80-degrees-C with a CO pressure of 1-2 atm resulted in the quantitative formation of creamy white bis(carbonyl)platinum(II) fluorosulfate, Pt(CO)2(SO3F)2. The corresponding bis(carbonyl)palladium(II) fluorosulfate, Pd(CO)2(SO3F)2, has been formed from solid Pd(II)Pd(IV)(SO3F)6 at room temperature and a CO pressure of 0.5 atm as a yellow solid that was thermally stable up to 117-degrees-C. Both compounds gave nearly identical IR and Raman spectra, which suggests a cis-square-planar configuration. The average CO stretching frequencies were at 2217 and 2201 cm-1 for Pd(CO)2(SO3F)2 and Pt(CO)2(SO3F)2, respectively. They are unusually high and suggest substantially reduced pi-back-donation. Pd(CO)2(SO3F)2 is the first example of a thermally stable mononuclear bis(carbonyl) derivative of dipositive palladium.},
	keywords = {CARBONYL-COMPLEXES, DERIVATIVES, GOLD(III) FLUOROSULFATE, ION, LATE TRANSITION-ELEMENTS, PALLADIUM(II)},
	isbn = {0022-1139},
	url = {<Go to ISI>://A1994MX36700013},
	author = {Hwang, G. and Wang, C. and Bodenbinder, M. and Willner, H. and Aubke, F.}
}
