@article {729, title = {Synthesis and molecular structure of 4-methoxyphenyl-2 {\textquoteright}-pyrrolylthione and its rhenium complex}, journal = {Inorganica Chimica Acta}, volume = {349}, year = {2003}, note = {ISI Document Delivery No.: 692RBTimes Cited: 4Cited Reference Count: 17}, month = {Jun}, pages = {58-64}, type = {Article}, abstract = {{A bidentate monoanionic N,S-ligand, 4-methoxyphenyl-2{\textquoteright}-pyrrolylthione (1) was synthesised via an oxygen-to-sulphur exchange in the corresponding ketone and then fully characterised. A trinuclear complex (2) of rhenium with this compound was obtained in a reaction of KReO4 with 1 in the presence of a reducing agent in aqueous ethanol, followed by slow precipitation from chloroform-hexane. The structure of compound 2 corresponds to the formula [Re3O4(C12H10NOS)(6)](+1)[ReO4](-1).2CH(3)CH(2)OH. A single crystal X-ray diffraction study was performed for this complex. The following crystal data were obtained for 2: M-r = 2262.556, monoclinic, space group C2/c}, keywords = {4-methoxyphenyl-2 {\textquoteright}-pyrrolylthione, CRYSTAL-STRUCTURE, LIGAND, N, S-ligand, X-ray diffraction study}, isbn = {0020-1693}, url = {://000183673100008}, author = {Selivanova, S. V. and Dolphin, D. and van Lier, J. E. and Kudrevich, S. V.} }