@article {1475,
	title = {Substituent effects in the hydrosilylation of coordinated dinitrogen in a ditantalum complex: Cleavage and functionalization of N-2},
	journal = {Journal of the American Chemical Society},
	volume = {128},
	number = {29},
	year = {2006},
	note = {ISI Document Delivery No.: 064WLTimes Cited: 19Cited Reference Count: 44MacKay, Bruce A. Munha, Rui F. Fryzuk, Michael D.},
	month = {Jul},
	pages = {9472-9483},
	type = {Article},
	abstract = {{The dinitrogen complex ([NPN]Ta)(2)(mu(1)-eta(2):eta(2)-N-2)(mu-H)(2), 1, (where [NPN] = (PhNSiMe2CH2)(2)PPh) undergoes hydrosilylation with primary and secondary alkyl- and arylsilanes, giving a new N-Si bond and a new terminal tantalum hydride derived from one Si-H unit. Various primary silanes can be employed to give isolable complexes of the general formula ([NPN]TaH)(mu-N-N-SiHnR3-n)(mu-H)(2)(Ta[NPN]) (5},
	keywords = {CATALYTIC-REDUCTION, END-ON, LIGAND, METAL-COMPLEXES, MOLECULAR NITROGEN, MOLYBDENUM, N BOND-CLEAVAGE, SIDE-ON, TERMINAL ALKYNES, TRIAMIDOAMINE COMPLEXES},
	isbn = {0002-7863},
	url = {<Go to ISI>://000239120700063},
	author = {MacKay, B. A. and Munha, R. F. and Fryzuk,Michael D.}
}
