@article {7233,
	title = {SYNTHESIS AND REACTIVITY OF THE IRIDIUM VINYLIDENE IR=C=CH2[N(SIME2CH2PPH2)2] - FORMATION OF CARBON-CARBON BONDS VIA MIGRATORY INSERTION OF A VINYLIDENE UNIT},
	journal = {Organometallics},
	volume = {11},
	number = {9},
	year = {1992},
	note = {ISI Document Delivery No.: JN066Times Cited: 75Cited Reference Count: 42},
	month = {Sep},
	pages = {2979-2990},
	type = {Article},
	abstract = {{The synthesis of the 16-electron iridium vinylidene complex Ir=C=CH2[N(SiMe2CH2PPh2)2] is described by starting from the cyclooctene derivative Ir(eta-2-C8H14)[N(SiMe2CH2PPh2)2] with addition of acetylene. This vinylidene complex reacts with a variety of electrophiles; thus, reaction with AlR3 (R = Me, Et) or GaMe3 leads to the formation of the new derivatives Ir(ER2)CR=CH2[N(SiMe2CH2PPh2)2] (E = Al},
	keywords = {ACETYLIDE COMPLEXES, ALKYNE, CARBENE, COMPLEX, FISCHER-TROPSCH REACTION, LIGAND, MECHANISM, PHOTOINDUCED RING EXPANSION, REARRANGEMENT, SATURATED CARBON, TRANSITION-METAL},
	isbn = {0276-7333},
	url = {<Go to ISI>://A1992JN06600009},
	author = {Fryzuk,Michael D. and Huang, L. and McManus, N. T. and Paglia, P. and Rettig, S. J. and White, G. S.}
}
