@article {7014,
	title = {PHOSPHINE COMPLEXES OF YTTRIUM, LANTHANUM, AND LUTETIUM - SYNTHESIS, THERMOLYSIS, AND FLUXIONAL BEHAVIOR OF THE HYDROCARBYL DERIVATIVES MR{\textquoteright}[N(SIME2CH2PME2)2]2 - X-RAY CRYSTAL-STRUCTURE OF Y[N(SIME2CHPME2)(SIME2CH2PME2)][N(SIME2CH2PME2)2]},
	journal = {Organometallics},
	volume = {10},
	number = {6},
	year = {1991},
	note = {ISI Document Delivery No.: FQ933Times Cited: 61Cited Reference Count: 41},
	month = {Jun},
	pages = {2026-2036},
	type = {Article},
	abstract = {{The preparation of phosphine complexes of the group 3 elements yttrium and lanthanum and the lanthanide metal lutetium is described. The reaction of 2 equiv of lithium salt of the mixed-donor ligand LiN(SiMe2CH2PR2)2 (R = Me, Ph, Pr(i)) with YCl3 or LuCl3 (R = Me only) leads to the formation of the bis(ligand) complexes MCl[N(SiMe2CH2PR2)2]2. The analogous lanthanum derivative requires the use of the corresponding potassium salt KN(SiMe2CH2PR2)2 (R = Me, Ph) with anhydrous LaCl3 to generate good yields of LaCl(N(SiMe2CH2PR2)2]2. Replacement of the remaining chloride with a hydrocarbyl ligand can be achieved for M = Y and Lu to generate MR[N(SiMe2CH2PMe2)2]2 (M = Y},
	keywords = {ALKYL, BOND ACTIVATION, CHEMISTRY, CRYSTALLOGRAPHIC CHARACTERIZATION, ELIMINATION, F-BLOCK METALS, HAFNIUM(IV), hydride, LIGAND, ORGANOLANTHANIDES},
	isbn = {0276-7333},
	url = {<Go to ISI>://A1991FQ93300059},
	author = {Fryzuk,Michael D. and Haddad, T. S. and Rettig, S. J.}
}
