@article {3041,
	title = {NMR INVESTIGATIONS OF THE POSSIBLE CROSS-REACTIONS BETWEEN CYANATE AND EPOXY-RESINS},
	journal = {Journal of Polymer Science Part a-Polymer Chemistry},
	volume = {32},
	number = {12},
	year = {1994},
	note = {ISI Document Delivery No.: PC784Times Cited: 25Cited Reference Count: 11},
	month = {Sep},
	pages = {2203-2221},
	type = {Article},
	abstract = {The possible cross reactions indicated by solid-state NMR between cyanate functionalized resin and epoxy functionalized resin have been investigated by using both natural abundance and labeled monofunctional model compounds. These soluble products were isolated and purified by silica gel adsorption chromatography and gel permeation chromatography. They were fully characterized by high resolution H{\textendash}1, C{\textendash}13, N-15-NMR spectroscopy and by mass spectrometry. The major cross-reaction product is a racemic mixture of enantiomers, which contain an oxazolidinone ring formed by one cyanate molecule and two epoxy molecules. However, epoxy consumption lags cyanate consumption in the overall reaction as triazine formation from the cyanate is much faster than the two competing reactions, the cross reaction between cyanate and epoxy, and the self-polymerization of epoxy, under the conditions investigated. The cross reaction between cyanate and epoxy is limited. Approximately 12\% of cross reaction between cyanate and epoxy was found in the overall reaction. In addition to the cross reactions of epoxy and cyanate, the reactions of epoxy and the carbamate, which is the major side product for the curing reaction of cyanate resin in solution, have also been investigated, and the mechanism of these reactions discussed. From the reactions of epoxy and carbamate, several products related to cross reaction between epoxy and cyanate have been isolated and identified. It is suggested that the reaction of epoxy and carbamate is one of the pathways in the overall cross reaction between epoxy and cyanate resins. Finally, the mechanism of the overall cross-curing reaction between the diepoxy and dicyanate mixed resins is discussed. (C) 1994 John Wiley \& Sons, Inc.},
	keywords = {AND H-1-NMR, C-13-NMR, CARBAMATE, CROSS REACTION, CURING, CYANATE, EPOXY, MIXED RESINS, N-15-NMR, OXAZOLIDINONE},
	isbn = {0887-624X},
	url = {<Go to ISI>://A1994PC78400001},
	author = {Fyfe, C. A. and Niu, J. and Rettig, S. J. and Wang, D. W. and Poliks, M. D.}
}
