@article {2918,
	title = {N-14 QUADRUPOLE COUPLING-CONSTANTS AND N-14 AND F-19 SPIN ROTATION COUPLING-CONSTANTS OF NITROSYL FLUORIDE, FNO, AND NITRYL FLUORIDE, FNO2},
	journal = {Journal of the Chemical Society-Faraday Transactions},
	volume = {89},
	number = {12},
	year = {1993},
	note = {ISI Document Delivery No.: LJ598Times Cited: 13Cited Reference Count: 29},
	month = {Jun},
	pages = {1899-1902},
	type = {Article},
	abstract = {High-resolution pure rotational spectra of nitrosyl fluoride, FNO, and nitryl fluoride, FNO2, have been measured using a cavity pulsed microwave Fourier-transform spectrometer. The samples were prepared using a pulsed electric discharge through precursor substances, with the discharge apparatus mounted as part of the pulsed nozzle of the spectrometer. Nuclear quadrupole and magnetic hyperfine structures due to N-14 and F-19 have been resolved for both molecules, and precise values for the nuclear quadrupole and spin-rotation coupling constants have been obtained. The N-14 quadrupole coupling constants of FNO2 have been rationalized in terms of a sigma-withdrawal of electron density from NO2 towards F. This view is corroborated by the magnetic shielding estimated from the F spin-rotation constants.},
	keywords = {MICROWAVE},
	isbn = {0956-5000},
	url = {<Go to ISI>://A1993LJ59800002},
	author = {Styger, C. and Gatehouse, B. and Heineking, N. and Jager, W. and Gerry, M. C. L.}
}
