@article {4339, title = {The co-crystallization of Ru((R)-binap)(eta(3)-Me-allyl)(2) and binap dioxide, and synthesis of Ru(Ph2P(CH2)(4)PPh2)(eta(3)-Me-allyl)(2)}, journal = {Journal of Organometallic Chemistry}, volume = {557}, number = {2}, year = {1998}, note = {ISI Document Delivery No.: ZQ872Times Cited: 8Cited Reference Count: 30}, month = {Apr}, pages = {213-219}, type = {Article}, abstract = {{The molecular structure of the 2-methylallyl species Ru((R)-binap)(eta(3)-Me-allyl)(2) (3) was established by X-ray crystallography of a crystal of 3a, the asymmetric unit of which is composed of half of a molecule of 3 and half of a (R)-(+)-2,2{\textquoteright}-bis(-diphenylphosphinoyl)-1,1{\textquoteright}-binaphthyl(binap dioxide) molecule, co-crystallized with two disordered deuterobenzenes; crystals of 3a are tetragonal, space group I422, with Z = 8}, keywords = {allyl, ASYMMETRIC HYDROGENATION, BINAP, CATALYSTS, COMPLEXES, ENANTIOSELECTIVE HYDROGENATION, GENERAL-SYNTHESIS, KINETICS, rhodium, ruthenium, RUTHENIUM(II) COMPLEXES, X-ray crystal structure}, isbn = {0022-328X}, url = {://000073911500007}, author = {Macfarlane, K. S. and Rettig, S. J. and Liu, Z. Q. and James, Brian R.} }