@article {2593,
	title = {Unprecedented Reactivity Initiated by Insertion of 2,6-Xylylisonitrile into the W-Alkyl Linkages of Cp*W(NO)(n-alkyl)(eta(3)-CH2CHCHMe) Complexes},
	journal = {Organometallics},
	volume = {28},
	number = {21},
	year = {2009},
	note = {ISI Document Delivery No.: 511VVTimes Cited: 1Cited Reference Count: 7Semproni, Scott P. Legzdins, Peter},
	month = {Nov},
	pages = {6139-6141},
	type = {Article},
	abstract = {Treatment of the compounds Cp*W(NO)(R)(eta(3)- CH2CHCHMe) (R = n-C5H11, n-C7H15, n-C8H17) with 2,6-xylylisonitrile first produces the expected complexes bearing eta(2)-iminoacyl ligands arising from migratory insertion of the isonitrile into the tungsten-alkyl linkages, processes that result in the allyl ligands undergoing concomitant eta(3) -> eta(1) haptotropic shifts. These eta(1)-allyl complexes then undergo subsequent intramolecular nucleophilic attacks by their allyl groups on the nitrogen atoms of the eta(2)-iminoacyl ligands to form novel metallacyclic compounds that contain alpha-aminocarbene ligands.},
	isbn = {0276-7333},
	url = {<Go to ISI>://000271200300001},
	author = {Semproni, S. P. and Legzdins,Peter}
}
