@article {2785, title = {REACTIONS OF 16-ELECTRON CP{\textquoteright}M(NO)R2 COMPOUNDS [M = MO, W R = ALKYL, ARYL] WITH CARBON-MONOXIDE}, journal = {Organometallics}, volume = {12}, number = {6}, year = {1993}, note = {ISI Document Delivery No.: LG158Times Cited: 14Cited Reference Count: 28}, month = {Jun}, pages = {2085-2093}, type = {Article}, abstract = {{This paper reports the reactions of 16-electron Cp{\textquoteright}M(NO)R2 complexes [Cp{\textquoteright} = CP (eta5-C5H5), Cp* (eta5-C5Me5); M = Mo, W; R = alkyl, aryl] with carbon monoxide. The reactions proceed in a stepwise fashion, and their outcomes are dependent on both the natures of Cp{\textquoteright} and R and the experimental conditions employed. Thus, treatment of solutions of Cp{\textquoteright}W(NO)R2 with CO under ambient conditions affords the corresponding 18-electron monoacyl species Cp{\textquoteright}W(NO)-(eta2-C{O}R) (R) (Cp{\textquoteright} = Cp*}, keywords = {COORDINATION, CRYSTAL, ETA-2-ACYL COMPLEXES, MOLYBDENUM, ORGANOMETALLIC NITROSYL CHEMISTRY, TUNGSTEN}, isbn = {0276-7333}, url = {://A1993LG15800019}, author = {Dryden, N. H. and Legzdins,Peter and Lundmark, P. J. and Riesen, A. and Einstein, F. W. B.} }