@article {7218, title = {ORGANOMETALLIC NITROSYL CHEMISTRY .53. SYNTHESIS, CHARACTERIZATION, AND PROPERTIES OF 16-ELECTRON CP-ASTERISK-M(NO)(ARYL)2 (M = MO, W) COMPLEXES}, journal = {Organometallics}, volume = {11}, number = {7}, year = {1992}, note = {ISI Document Delivery No.: JD622Times Cited: 37Cited Reference Count: 28}, month = {Jul}, pages = {2583-2590}, type = {Article}, abstract = {{Treatment of Cp*M(NO)Cl2 (Cp* = eta-5-C5Me5; M = Mo, W) in THF at low temperatures with equimolar amounts of diarylmagnesium reagents, (aryl)2Mg.x(dioxane), affords the diaryl complexes Cp*M(NO)(aryl)2 (aryl = Ph, o-tolyl, or p-tolyl), which are isolable in moderate yields and have been fully characterized by conventional spectroscopic methods. In addition, single-crystal X-ray crystallographic analyses have been performed on both o-tolyl complexes. Crystal data for Cp*Mo(NO)(o-tolyl)2 (3): a = 11.570 (2) angstrom}, keywords = {MOLYBDENUM, TUNGSTEN}, isbn = {0276-7333}, url = {://A1992JD62200048}, author = {Dryden, N. H. and Legzdins,Peter and Rettig, S. J. and Veltheer, J. E.} }