@article {3389,
	title = {DETERMINATION OF THE MOLECULAR-CONSTANTS FOR INTERACTING BRIGHT AND DARK STATES - ANALYSIS OF THE HIGH-RESOLUTION INFRARED-SPECTRUM OF THE NU(8) BAND OF SULFINE, H2CSO},
	journal = {Journal of Molecular Spectroscopy},
	volume = {171},
	number = {1},
	year = {1995},
	note = {ISI Document Delivery No.: QW672Times Cited: 6Cited Reference Count: 17},
	month = {May},
	pages = {113-124},
	type = {Article},
	abstract = {Gas-phase infrared spectra of the transient molecule sulfine, H2CSO, have been recorded in pyrolysis experiments using methanesulfinyl chloride or dimethyl sulfoxide as starting materials. Two strong vibrational fundamentals, upsilon(4) (a{\textquoteright}, 1175 cm(-1)) and upsilon(8) (a {\textquoteright}{\textquoteright} 762 cm(-1)), have been observed at low resolution in the 1400-700 cm(-1) region. The upsilon(8) band has been recorded at high resolution and a detailed analysis of the rotational structure has been carried out. Numerous excited state perturbations result from Δ K-a\ = 2 A-type and Δ K-a\ = 1 B-type Coriolis interactions with the 7(2) vibrational state at 784.2 cm(-1). Although 2 upsilon(7) band transitions could not be directly observed, a complete analysis of the perturbed rotational, structure has been possible, using a Hamiltonian which includes both types of Coriolis interactions. Accurate molecular constants have been obtained for both states with only two interaction constants, one for each mechanism. A few weak perturbations at very high K-a values could not be fitted with this scheme and are assigned to high order Coriolis interactions with the 6(1) level at 866 cm(-1). (C) 1995 Academic Press, Inc.},
	isbn = {0022-2852},
	url = {<Go to ISI>://A1995QW67200008},
	author = {Joo, D. L. and Clouthier, D. J. and Chan, C. P. and Lai, V. W. M. and Ma, E. S. F. and Merer, A. J.}
}
