@article {1601, title = {A pentagonal pyramidal zirconium imido complex for catalytic hydroamination of unactivated alkenes}, journal = {Organometallics}, volume = {25}, number = {17}, year = {2006}, note = {ISI Document Delivery No.: 070PZTimes Cited: 66Cited Reference Count: 40Thomson, Robert K. Bexrud, Jason A. Schafer, Laurel L.}, month = {Aug}, pages = {4069-4071}, type = {Article}, abstract = {The first, isolable group 4 imido complexes capable of promoting intramolecular olefin hydroamination for the preparation of N-containing heterocycles are presented. The structurally characterized 6-coordinate bis(amidate)-supported zirconium imido complex is a rare example of distorted-pentagonal-pyramidal geometry.}, keywords = {ALKYNE HYDROAMINATION, allenes, AMIDATE COMPLEXES, BIS(AMIDATE) TITANIUM PRECATALYST, C-H ACTIVATION, HYDROAMINATION, INTERMOLECULAR HYDROAMINATION, INTRAMOLECULAR, REACTIVITY, TEMPERATURE, TI(NME2)(4)}, isbn = {0276-7333}, url = {://000239536800007}, author = {Thomson, R. K. and Bexrud, J. A. and Schafer, L. L.} }