@article {5232,
	title = {Chemistry of Re with N,N {\textquoteright}-bis(2-pyridylmethyl)ethylenediamine (H(2)pmen): Hydrolysis, dehydrogenation, and ternary complexes},
	journal = {Inorganic Chemistry},
	volume = {40},
	number = {9},
	year = {2001},
	note = {ISI Document Delivery No.: 423DBTimes Cited: 13Cited Reference Count: 49},
	month = {Apr},
	pages = {2005-2010},
	type = {Article},
	abstract = {A number of Re complexes with N,N {\textquoteright} -bis(2-pyridylmethyl)ethylenediamine (H(2)pmen) have been made from [NH4]-[ReO4]. . [ReOCl(2)H(2)pmen)]Cl, [ReOCl(Hpmen)][ReO4], and [ReO2(H(2)pmen)] [ReO4] are related by hydrolysis/HCl substitution [ReOCl(Hpmen)] [ReO4] was structurally characterized and found to contain a water-stable amido-Re bend. Dehydrogenation of the N-donor ligand from each amine to imine with concomitant two-electron reduction of the Re center occurs readily in these systems. With suitable 3-hydroxy-4-pyrones, ternary complexes such as [(ReCl)-Cl-III(ma)(C14H14N4)][ReO4]. CH3OH, 5, were made from [NH4][ReO4], H(2)pmen . 4HCl and pyrones in one-pot syntheses. 5, a seven-coordinate Re-III complex, was structurally characterized.},
	keywords = {aluminum, CHELATE COMPLEXES, COORDINATION-COMPOUNDS, gallium, LIGANDS, RADIOPHARMACEUTICALS, RAY CRYSTAL-STRUCTURE, Rhenium complexes, technetium, TRIS(2-PYRIDYLMETHYL)AMINE},
	isbn = {0020-1669},
	url = {<Go to ISI>://000168159200007},
	author = {Xu, L. and Pierreroy, J. and Patrick, B. O. and Orvig, Chris}
}
@article {4983,
	title = {Seven-coordinate [(ReON4X2)-O-V](+) complexes (X = O and Cl)},
	journal = {Inorganic Chemistry},
	volume = {39},
	number = {26},
	year = {2000},
	note = {ISI Document Delivery No.: 385TFTimes Cited: 10Cited Reference Count: 29},
	month = {Dec},
	pages = {5958-5963},
	type = {Article},
	abstract = {The oxorhenium(V) complexes with ligands containing N-4 (H(2)pmen) and N4O2 (H(2)bbpen, H(2)Clbbpen, and H(2)bped) donor atom sets have been synthesized. X-ray crystallographic analyses of the [ReO(H(2)pmen)Cl-2](+), [ReO(bbpen)](+), and [ReO(bped)](+) complexes showed that all three cations share a rate seven-coordinate structure with a distorted pentagonal bipyramidal geometry, which represents a novel and potentially general structural motif in Re-V=O complexes. H-1 NMR spectroscopy shows that the structures of the complexes are retained in the solution.},
	keywords = {CHELATION, CHEMISTRY, LIGANDS, N3O2, pyridyl, RADIOPHARMACEUTICALS, rhenium, technetium, TRIS(2-PYRIDYLMETHYL)AMINE},
	isbn = {0020-1669},
	url = {<Go to ISI>://000166019200010},
	author = {Xu, L. and Setyawati, I. A. and Pierreroy, J. and Pink, M. and Young, V. G. and Patrick, B. O. and Rettig, S. J. and Orvig, Chris}
}
