@article {4961,
	title = {{The reactions of the third transition series metal hexafluorides, MF6},
	journal = {Journal of Fluorine Chemistry},
	volume = {102},
	number = {1-2},
	year = {2000},
	note = {ISI Document Delivery No.: 302YMTimes Cited: 8Cited Reference Count: 77},
	month = {Mar},
	pages = {243-252},
	type = {Article},
	abstract = {{The reactions of the third transition (5d) series metal hexafluorides PtF6, IrF6, OsF6, ReF6 and WF6 with CO are studied in the Lewis superacid SbF5, the Bronsted superacid HF and the conjugate Bronsted-Lewis superacid HF-SbF5, in order to evaluate their potential as reactants in reductive carbonylations. These reactions are aimed at the generation of homoleptic metal carbonyl cations of the type [M(CO)(n)](m+)},
	keywords = {<IR(CO)(6)>(3+), carbonyl fluoride, CO, FLUOROSULFATES, HEXACARBONYLS, homoleptic carbonyl complexes, INCLUDING STEREOISOMERS, metal hexafluorides, MOLECULAR-STRUCTURE, NOBLE-METALS, PALLADIUM(II), platinum, superacid, UNDECAFLUORODIANTIMONATE(V), VIBRATIONAL-SPECTRA},
	isbn = {0022-1139},
	url = {<Go to ISI>://000086394100033},
	author = {von Ahsen, B. and Bach, C. and Pernice, H. and Willner, H. and Aubke, F.}
}
@article {3844,
	title = {Homoleptic carbonyl cations of palladium(I), palladium(II), platinum(II), and gold(I) - Simplified synthetic routes to their fluoroantimonate(V) salts},
	journal = {Canadian Journal of Chemistry-Revue Canadienne De Chimie},
	volume = {74},
	number = {11},
	year = {1996},
	note = {ISI Document Delivery No.: WC124Times Cited: 8Cited Reference Count: 68},
	month = {Nov},
	pages = {1952-1958},
	type = {Article},
	abstract = {{The original synthetic routes to the new noble metal carbonyl cations [Au(CO)(2)](+) and [M(CO)(4)](2+)},
	keywords = {ACIDS, and Pt(II), carbonylations in strong acidic media, COMPLEXES, DERIVATIVES, FLUOROSULFATES, MAS NMR-SPECTRA, metal carbonyl cations of Au(I), MONOXIDE, NOBLE-METALS, Pd(I), Pd(II), reactions in liquid SbF5, reductive carbonylation in liquid SbF5, solvolysis, UNDECAFLUORODIANTIMONATE(V), VIBRATIONAL-SPECTRA},
	isbn = {0008-4042},
	url = {<Go to ISI>://A1996WC12400009},
	author = {Wang, C. Q. and Siu, S. C. and Hwang, G. and Bach, C. and Bley, B. and Bodenbinder, M. and Willner, H. and Aubke, F.}
}
@article {3842,
	title = {Solvolysis reactions in liquid antimony (V) fluoride. A convenient and versatile synthetic method},
	journal = {European Journal of Solid State and Inorganic Chemistry},
	volume = {33},
	number = {9},
	year = {1996},
	note = {ISI Document Delivery No.: VK527Times Cited: 9Cited Reference Count: 71},
	pages = {917-930},
	type = {Article},
	abstract = {{Solvolysis reactions of various fluorosulfates in liquid antimony (V) fluoride allow the synthesis of a wide range of fluoroantimonate (V) salts with main group, organometallic and transition metal cations. In the presence of carbon monoxide, CO, at pressures of 0.5 to 2.0 atmospheres a new group of homoleptic carbonyl cations of electronrich metals (Hg, Au, Pt, Pd, Ir, Ru, and Os) form with [Sb2F11](-) as anion. The salts show relatively high thermal stability (> 100 degrees C). The geometries of the cations [Au(CO)(2)](+), [Hg(CO)(2)](2+) (linear) and [M(CO)(4)](2+)},
	keywords = {CATIONS, CRYSTAL, FLUOROSULFATES, MAGNETIC-PROPERTIES, MAS NMR-SPECTRA, MOLECULAR-STRUCTURE, NOBLE-METALS, TRIS(FLUOROSULFATE), UNDECAFLUORODIANTIMONATE(V), VIBRATIONAL-SPECTRA},
	isbn = {0992-4361},
	url = {<Go to ISI>://A1996VK52700012},
	author = {Wang, C. and Hwang, G. and Siu, S. C. and Aubke, F. and Bley, B. and Bodenbinder, M. and Bach, C. and Willner, H.}
}
@article {3843,
	title = {Synthesis, molecular structure, and vibrational spectra of mer-tris(carbonyl)iridium(III)fluorosulfate, mer-Ir(CO)(3)(SO3F)(3)},
	journal = {Inorganic Chemistry},
	volume = {35},
	number = {5},
	year = {1996},
	note = {ISI Document Delivery No.: TY260Times Cited: 21Cited Reference Count: 36},
	month = {Feb},
	pages = {1279-1285},
	type = {Article},
	abstract = {{Addition of carbon monoxide (0.5-2 atm) to iridium(III) fluorosulfate, Ir(SO3F)(3), dissolved in HSO3F over 4 days and at 60 degrees C, results in the quantitative formation of tris(carbonyl)iridium(III) fluorosulfate Ir(CO)(3)(SO3F)(3) Slow evaporation of the solvent produces single crystals of mer-Ir(CO)(3)(SO3F)(3). Crystal structure data for mer-Ir(CO)(3)(SO3F)(3): monoclinic, space group P2(1)/c},
	keywords = {DERIVATIVES, FLUOROSULFATES, GOLD, palladium, SYSTEM, UNDECAFLUORODIANTIMONATE(V)},
	isbn = {0020-1669},
	url = {<Go to ISI>://A1996TY26000029},
	author = {Wang, C. Q. and Lewis, A. R. and Batchelor, R. J. and Einstein, F. W. B. and Willner, H. and Aubke, F.}
}
@article {3541,
	title = {NEW HOMOLEPTIC METAL-CARBONYL CATIONS - THE SYNTHESES, VIBRATIONAL AND C-13 MAS NMR-SPECTRA OF HEXACARBONYL-RUTHENIUM(II) AND HEXACARBONYL-OSMIUM(II) UNDECAFLUORODIANTIMONATE(V), [RU(CO)(6)][SB2F11](2) AND [OS(CO)(6)][SB2F11](2)},
	journal = {Journal of the Chemical Society-Chemical Communications},
	number = {20},
	year = {1995},
	note = {ISI Document Delivery No.: TB415Times Cited: 38Cited Reference Count: 22},
	month = {Oct},
	pages = {2071-2072},
	type = {Article},
	abstract = {The new homoleptic carbonyl cations [Ru(CO)(6)](2+) and [Os(CO)(6)](2+) are obtained as [Sb2F11](-) salts by the reductive carbonylation of M(SO3F)(3) (M = Ru, Os), under very mild conditions (60-90 degrees C, 1 atm CO), in liquid SbF5 in a simple, one-step procedure, and are characterized by FT Raman, FTIR and C-13 MAS NMR spectroscopy.},
	keywords = {FLUOROSULFATES, NOBLE-METALS},
	isbn = {0022-4936},
	url = {<Go to ISI>://A1995TB41500013},
	author = {Wang, C. Q. and Bley, B. and Balzerjollenbeck, G. and Lewis, A. R. and Siu, S. C. and Willner, H. and Aubke, F.}
}
