@article {3842,
	title = {Solvolysis reactions in liquid antimony (V) fluoride. A convenient and versatile synthetic method},
	journal = {European Journal of Solid State and Inorganic Chemistry},
	volume = {33},
	number = {9},
	year = {1996},
	note = {ISI Document Delivery No.: VK527Times Cited: 9Cited Reference Count: 71},
	pages = {917-930},
	type = {Article},
	abstract = {{Solvolysis reactions of various fluorosulfates in liquid antimony (V) fluoride allow the synthesis of a wide range of fluoroantimonate (V) salts with main group, organometallic and transition metal cations. In the presence of carbon monoxide, CO, at pressures of 0.5 to 2.0 atmospheres a new group of homoleptic carbonyl cations of electronrich metals (Hg, Au, Pt, Pd, Ir, Ru, and Os) form with [Sb2F11](-) as anion. The salts show relatively high thermal stability (> 100 degrees C). The geometries of the cations [Au(CO)(2)](+), [Hg(CO)(2)](2+) (linear) and [M(CO)(4)](2+)},
	keywords = {CATIONS, CRYSTAL, FLUOROSULFATES, MAGNETIC-PROPERTIES, MAS NMR-SPECTRA, MOLECULAR-STRUCTURE, NOBLE-METALS, TRIS(FLUOROSULFATE), UNDECAFLUORODIANTIMONATE(V), VIBRATIONAL-SPECTRA},
	isbn = {0992-4361},
	url = {<Go to ISI>://A1996VK52700012},
	author = {Wang, C. and Hwang, G. and Siu, S. C. and Aubke, F. and Bley, B. and Bodenbinder, M. and Bach, C. and Willner, H.}
}
@article {3866,
	title = {Superacid anions: Crystal and molecular structures of oxonium undecafluorodiantimonate(V), [H3O][Sb2F11], cesium fluorosulfate, CsSO3F, cesium hydrogen bis(fluorosulfate), Cs[H(SO3F)(2)], cesium tetrakis(fluorosulfato)aurate(III), Cs[Au(SO3F)(4)], cesium},
	journal = {Inorganic Chemistry},
	volume = {35},
	number = {21},
	year = {1996},
	note = {ISI Document Delivery No.: VL611Times Cited: 31Cited Reference Count: 90},
	month = {Oct},
	pages = {6113-6130},
	type = {Article},
	abstract = {{In order to understand the reasons for the low nucleophilicity of superacid anions, a systematic, comparative study of six superacid anions by single-crystal X-ray diffraction is undertaken. From magic acid, HSO3F-SbF5, surprisingly, single crystals of oxonium undecafluorodiantimonate(V), [H3O][Sb2F11], 1, are obtained. In the remaining five salts the cesium ion, Cs+, is used as the countercation. Both CsSO3F, 2, and its solvate Cs[H(SO3F)(2)], 3, are derived from the Bronsted superacid HSO3F. The conjugate noble metal superacid systems HSO3F-Au(SO3F)(3) and HSO3F-Pt(SO3F)(4) provide cesium tetrakis(fluorosulfato)aurate(III) Cs[Au(SO3F)(4)], 4, and cesium hexakis (fluorosulfato)platinate(IV) Cs-2[Pt(SO3F)(6)], 5. Cesium hexakis (fluorosulfato)antimonate(V) Cs[Sb(SO3F)(6)], 6, whose synthesis is described here in detail, provides evidence for the possible existence of a new conjugate superacid system, HSO3F-Sb(SO3F)(5). Crystals of [H3O][Sb2F11] (1, H3F11OSb2) are orthorhombic},
	keywords = {ACIDS, BEHAVIOR, CATIONS, CONSTANTS, DERIVATIVES, FLUORIDE, FLUOROSULFATE, GOLD(III), TRIS(FLUOROSULFATE), VIBRATIONAL-SPECTRA, WEAKLY COORDINATING ANIONS},
	isbn = {0020-1669},
	url = {<Go to ISI>://A1996VL61100024},
	author = {Zhang, D. L. and Rettig, S. J. and Trotter, J. and Aubke, F.}
}
@article {3866,
	title = {Superacid anions: Crystal and molecular structures of oxonium undecafluorodiantimonate(V), [H3O][Sb2F11], cesium fluorosulfate, CsSO3F, cesium hydrogen bis(fluorosulfate), Cs[H(SO3F)(2)], cesium tetrakis(fluorosulfato)aurate(III), Cs[Au(SO3F)(4)], cesium},
	journal = {Inorganic Chemistry},
	volume = {35},
	number = {21},
	year = {1996},
	note = {ISI Document Delivery No.: VL611Times Cited: 31Cited Reference Count: 90},
	month = {Oct},
	pages = {6113-6130},
	type = {Article},
	abstract = {{In order to understand the reasons for the low nucleophilicity of superacid anions, a systematic, comparative study of six superacid anions by single-crystal X-ray diffraction is undertaken. From magic acid, HSO3F-SbF5, surprisingly, single crystals of oxonium undecafluorodiantimonate(V), [H3O][Sb2F11], 1, are obtained. In the remaining five salts the cesium ion, Cs+, is used as the countercation. Both CsSO3F, 2, and its solvate Cs[H(SO3F)(2)], 3, are derived from the Bronsted superacid HSO3F. The conjugate noble metal superacid systems HSO3F-Au(SO3F)(3) and HSO3F-Pt(SO3F)(4) provide cesium tetrakis(fluorosulfato)aurate(III) Cs[Au(SO3F)(4)], 4, and cesium hexakis (fluorosulfato)platinate(IV) Cs-2[Pt(SO3F)(6)], 5. Cesium hexakis (fluorosulfato)antimonate(V) Cs[Sb(SO3F)(6)], 6, whose synthesis is described here in detail, provides evidence for the possible existence of a new conjugate superacid system, HSO3F-Sb(SO3F)(5). Crystals of [H3O][Sb2F11] (1, H3F11OSb2) are orthorhombic},
	keywords = {ACIDS, BEHAVIOR, CATIONS, CONSTANTS, DERIVATIVES, FLUORIDE, FLUOROSULFATE, GOLD(III), TRIS(FLUOROSULFATE), VIBRATIONAL-SPECTRA, WEAKLY COORDINATING ANIONS},
	isbn = {0020-1669},
	url = {<Go to ISI>://A1996VL61100024},
	author = {Zhang, D. L. and Rettig, S. J. and Trotter, J. and Aubke, F.}
}
@article {7380,
	title = {SELECTED REACTIONS OF FLUORINE-FLUOROSULFATE, FOSO2F},
	journal = {Journal of Fluorine Chemistry},
	volume = {59},
	number = {3},
	year = {1992},
	note = {ISI Document Delivery No.: KF321Times Cited: 8Cited Reference Count: 36},
	month = {Dec},
	pages = {333-349},
	type = {Article},
	abstract = {The reactions of fluorine-fluorosulfate, FOSO2F, with SSF2, SeF4, AsF3 and MoF5 have been studied, and its previously reported reactions with SF4, Br2 and I2 re-investigated in order to test its suitability as a synthetic reagent. All substrates reacted exothermically, and sometimes explosively, between 80-298 K. The presence of the byproducts obtained may be rationalized by the thermal decomposition of some of the FOSO2F, which proceeds along two pathways, i.e. FOSO2F {\textendash}> 1/2O2 + SO2F2 and FOSO2F {\textendash}> 1/2F2 + 1/2S2O6F2, during the extremely exothermic reactions via radical intermediates. The fluorine formed gives rise to fully fluorinated products, and the SO3F. radicals, initially formed, either dimerize to give S2O6F2 or decompose to O2 and S2O5F2. Element fluoride-fluorosulfates, when formed at all, were obtained in low yields only when SO2F2 or SO2FCl were used as suitable moderators. The complete vibrational spectra of EF5OSO2F (E = S, Se or Te) have been studied and assigned. The reactions of I2, Br2 and AsF3 with FOSO2F yielded viscous liquids of the approximate, non-stoichiometric composition EFn(SO5F)5-n (E = As or I) and EFn(SO3F)3-n (E = Br), with n = non-integral number. All compounds were characterized by their vibrational and F-19 NMR spectra, and in the case of SeF5OSO2F by Se-77 NMR methods.},
	keywords = {DERIVATIVES, GOLD(III) FLUOROSULFATE, halogen, ION, SPECTRA, TRIS(FLUOROSULFATE)},
	isbn = {0022-1139},
	url = {<Go to ISI>://A1992KF32100004},
	author = {Willner, H. and Mistry, F. and Aubke, F.}
}
