@article {3865,
	title = {The safe and convenient preparation of bis(fluorosulfuryl) peroxide (S2O6F2) on a large scale},
	journal = {Journal of Fluorine Chemistry},
	volume = {76},
	number = {1},
	year = {1996},
	note = {ISI Document Delivery No.: TW373Times Cited: 18Cited Reference Count: 20},
	month = {Jan},
	pages = {83-89},
	type = {Article},
	abstract = {The design and construction of a catalytic reactor (AgF2 on copper turnings as support) for the fluorination of SO3 in a flow reaction to produce bis(fluorosulfuryl) peroxide (S2O6F2) are described in detail. An operating procedure is developed that allows the production of S2O6F2 in substantial quantities (80-120 g h(-1)) and avoids the accidental production of fluorine fluorosulfate (FOSO2F) as a hazardous byproduct. Also described are purification methods and disposal procedures for highly reactive byproducts (F-2 or FOSO2F) in a safe and environmentally friendly manner, as well as the long-term storage of S2O6F2.},
	keywords = {AgF2 catalysis, bis(fluorosulfuryl), catalytic fluorination, DERIVATIVES, flow reactor design, FLUOROSULFATE, FOSO2F, peroxide synthesis},
	isbn = {0022-1139},
	url = {<Go to ISI>://A1996TW37300016},
	author = {Zhang, D. and Wang, C. and Mistry, F. and Powell, B. and Aubke, F.}
}
