@article {5127,
	title = {An aurophilicity-determined 3-D bimetallic coordination polymer: using [Au(CN)(2)](-) to increase structural dimensionality through gold center dot center dot center dot gold bonds in (tmeda)Cu[Au(CN)(2)](2)},
	journal = {Chemical Communications},
	number = {03},
	year = {2001},
	note = {ISI Document Delivery No.: 396KHTimes Cited: 68Cited Reference Count: 24},
	pages = {259-260},
	type = {Article},
	abstract = {A coordination polymer with the [Au(CN)(2)](-) building block has been prepared and it exhibits weak Au(I)-mediated ferromagnetic interactions; the structure illustrates that aurophilicity is a powerful tool to increase dimensionality, generating a three-dimensional system from a 1-D polymer.},
	keywords = {BUILDING-BLOCKS, CHEMISTRY, COMPONENT, CRYSTAL-STRUCTURE, LIGANDS, MAGNETIC-PROPERTIES, NETWORK},
	isbn = {1359-7345},
	url = {<Go to ISI>://000166635200017},
	author = {Leznoff, D. B. and Xue, B. Y. and Patrick, B. O. and Sanchez, V. and Thompson, R. C.}
}
@article {4984,
	title = {Coaggregation of paramagnetic d- and f-block metal ions with a podand-framework amine phenol ligand},
	journal = {Inorganic Chemistry},
	volume = {39},
	number = {3},
	year = {2000},
	note = {ISI Document Delivery No.: 283FQTimes Cited: 37Cited Reference Count: 86},
	month = {Feb},
	pages = {508-516},
	type = {Article},
	abstract = {This report covers initial studies in the coaggregation of nickel (Ni2+) and lanthanide (Ln(3+)) metal ions to form complexes with interesting structural and magnetic properties. The tripodal amine phenol ligand H(3)tam (1,1,1-tris(((2-hydroxybenzyl)amino)methyl)ethane) is shown to be particularly accommodating with respect to the geometric constraints of both transition and lanthanide metal ions, forming isolable complexes with both of these ion types. In the solid-state structure of [Ni(H(2)tam)(CH3CN)]PF6.2.5CH(3)CN.0.5CH(3)OH (1), the Ni(II) center has a distorted octahedral geometry, with an N3O2 donor set from the [H(2)tam](-) ligand and a coordinated solvent (acetonitrile) occupying the sixth site. The reaction of stoichiometric amounts of H(3)tam with the Ni(II) ion in the presence of lanthanide(III) ions provides [LnNi(2)(tam)(2)](+) cationic complexes which contain coaggregated metal ions. These complexes are isolable and have been characterized by a variety of analytical techniques, with mass spectrometry proving to be particularly diagnostic. The solid-state structures of [LaNi2(tam)(2)(CH3OH)(1/2)-(CH3CH2OH)(1/2)(H2O)]ClO4.0.5CH(3)OH.4H(2)O (2), [DyNi2(tam)(2)(CH3OH)(H2O)]ClO4.CH3OH.H2O (6), and [YbNi2(tam)(2)(H2O)]ClO4.2.58H(2)O (9) have been determined. Each complex contains two octahedral Ni(II) ions, each of which is encapsulated by the ligand tam(3-) in an N3O3 coordination sphere; each [Ni(tam)](-)unit caps the lanthanide(III) ion via bridging phenoxy oxygen donor atoms. In 2, La3+ is eight-coordinated, while in 6, Dy(III) is seven- (to "weakly eight-") coordinated, and Yb(III) in 9 has a six-coordination environment. The complexes are symmetrically different, 2 possessing C-1 symmetry and 6 and 9 having CI symmetry. Magnetic studies of 2, 6, and 9 indicate that antiferromagnetic exchange coupling between the Ni(II) and Ln(III) ions increases with decreasing ionic radius of Ln(III).},
	keywords = {AQUEOUS-SOLUTION, COMPARTMENTAL SCHIFF-BASES, COPPER-LANTHANOID COMPLEXES, CRYSTAL-STRUCTURES, DINICKEL(II) COMPLEXES, HEPTADENTATE LIGANDS, MACROCYCLIC COMPLEXES, MAGNETIC-PROPERTIES, MOLECULAR-STRUCTURE, SPIN-EXCHANGE},
	isbn = {0020-1669},
	url = {<Go to ISI>://000085266100018},
	author = {Xu, Z. Q. and Read, P. W. and Hibbs, D. E. and Hursthouse, M. B. and Malik, K. M. A. and Patrick, B. O. and Rettig, S. J. and Seid, M. and Summers, D. A. and Pink, M. and Thompson, R. C. and Orvig, Chris}
}
@article {4984,
	title = {Coaggregation of paramagnetic d- and f-block metal ions with a podand-framework amine phenol ligand},
	journal = {Inorganic Chemistry},
	volume = {39},
	number = {3},
	year = {2000},
	note = {ISI Document Delivery No.: 283FQTimes Cited: 37Cited Reference Count: 86},
	month = {Feb},
	pages = {508-516},
	type = {Article},
	abstract = {This report covers initial studies in the coaggregation of nickel (Ni2+) and lanthanide (Ln(3+)) metal ions to form complexes with interesting structural and magnetic properties. The tripodal amine phenol ligand H(3)tam (1,1,1-tris(((2-hydroxybenzyl)amino)methyl)ethane) is shown to be particularly accommodating with respect to the geometric constraints of both transition and lanthanide metal ions, forming isolable complexes with both of these ion types. In the solid-state structure of [Ni(H(2)tam)(CH3CN)]PF6.2.5CH(3)CN.0.5CH(3)OH (1), the Ni(II) center has a distorted octahedral geometry, with an N3O2 donor set from the [H(2)tam](-) ligand and a coordinated solvent (acetonitrile) occupying the sixth site. The reaction of stoichiometric amounts of H(3)tam with the Ni(II) ion in the presence of lanthanide(III) ions provides [LnNi(2)(tam)(2)](+) cationic complexes which contain coaggregated metal ions. These complexes are isolable and have been characterized by a variety of analytical techniques, with mass spectrometry proving to be particularly diagnostic. The solid-state structures of [LaNi2(tam)(2)(CH3OH)(1/2)-(CH3CH2OH)(1/2)(H2O)]ClO4.0.5CH(3)OH.4H(2)O (2), [DyNi2(tam)(2)(CH3OH)(H2O)]ClO4.CH3OH.H2O (6), and [YbNi2(tam)(2)(H2O)]ClO4.2.58H(2)O (9) have been determined. Each complex contains two octahedral Ni(II) ions, each of which is encapsulated by the ligand tam(3-) in an N3O3 coordination sphere; each [Ni(tam)](-)unit caps the lanthanide(III) ion via bridging phenoxy oxygen donor atoms. In 2, La3+ is eight-coordinated, while in 6, Dy(III) is seven- (to "weakly eight-") coordinated, and Yb(III) in 9 has a six-coordination environment. The complexes are symmetrically different, 2 possessing C-1 symmetry and 6 and 9 having CI symmetry. Magnetic studies of 2, 6, and 9 indicate that antiferromagnetic exchange coupling between the Ni(II) and Ln(III) ions increases with decreasing ionic radius of Ln(III).},
	keywords = {AQUEOUS-SOLUTION, COMPARTMENTAL SCHIFF-BASES, COPPER-LANTHANOID COMPLEXES, CRYSTAL-STRUCTURES, DINICKEL(II) COMPLEXES, HEPTADENTATE LIGANDS, MACROCYCLIC COMPLEXES, MAGNETIC-PROPERTIES, MOLECULAR-STRUCTURE, SPIN-EXCHANGE},
	isbn = {0020-1669},
	url = {<Go to ISI>://000085266100018},
	author = {Xu, Z. Q. and Read, P. W. and Hibbs, D. E. and Hursthouse, M. B. and Malik, K. M. A. and Patrick, B. O. and Rettig, S. J. and Seid, M. and Summers, D. A. and Pink, M. and Thompson, R. C. and Orvig, Chris}
}
@article {4914,
	title = {Polybis(4-azabenzimidazolato)-iron(II) and -cobalt(II). 3-D single diamond-like framework materials which exhibit spin canting and ferromagnetic ordering at low temperatures},
	journal = {Journal of the Chemical Society-Dalton Transactions},
	number = {21},
	year = {2000},
	note = {ISI Document Delivery No.: 374EATimes Cited: 31Cited Reference Count: 48},
	pages = {3931-3937},
	type = {Article},
	abstract = {{The direct reaction between ferrocene and an excess of molten 4-azabenzimidazole yielded amber-green crystals of polybis(4-azabenzimidazolato)iron(II), 1. Single crystal X-ray diffraction studies revealed tetrahedrally coordinated iron ions linked by single imidazolate bridges and forming a 3-D single diamond-like (diamondoid) extended lattice. Magnetization studies show the effects of antiferromagnetic exchange above a critical temperature},
	keywords = {CATIONS, COMPLEXES, CONSTRUCTION, coordination polymers, COPPER(I), CRYSTAL-STRUCTURES, LIGANDS, MAGNETIC-PROPERTIES, METAL PYRAZOLATE POLYMERS, NET},
	isbn = {1470-479X},
	url = {<Go to ISI>://000165330400026},
	author = {Rettig, S. J. and Sanchez, V. and Storr, A. and Thompson, R. C. and Trotter, J.}
}
@article {4914,
	title = {Polybis(4-azabenzimidazolato)-iron(II) and -cobalt(II). 3-D single diamond-like framework materials which exhibit spin canting and ferromagnetic ordering at low temperatures},
	journal = {Journal of the Chemical Society-Dalton Transactions},
	number = {21},
	year = {2000},
	note = {ISI Document Delivery No.: 374EATimes Cited: 31Cited Reference Count: 48},
	pages = {3931-3937},
	type = {Article},
	abstract = {{The direct reaction between ferrocene and an excess of molten 4-azabenzimidazole yielded amber-green crystals of polybis(4-azabenzimidazolato)iron(II), 1. Single crystal X-ray diffraction studies revealed tetrahedrally coordinated iron ions linked by single imidazolate bridges and forming a 3-D single diamond-like (diamondoid) extended lattice. Magnetization studies show the effects of antiferromagnetic exchange above a critical temperature},
	keywords = {CATIONS, COMPLEXES, CONSTRUCTION, coordination polymers, COPPER(I), CRYSTAL-STRUCTURES, LIGANDS, MAGNETIC-PROPERTIES, METAL PYRAZOLATE POLYMERS, NET},
	isbn = {1470-479X},
	url = {<Go to ISI>://000165330400026},
	author = {Rettig, S. J. and Sanchez, V. and Storr, A. and Thompson, R. C. and Trotter, J.}
}
@article {4914,
	title = {Polybis(4-azabenzimidazolato)-iron(II) and -cobalt(II). 3-D single diamond-like framework materials which exhibit spin canting and ferromagnetic ordering at low temperatures},
	journal = {Journal of the Chemical Society-Dalton Transactions},
	number = {21},
	year = {2000},
	note = {ISI Document Delivery No.: 374EATimes Cited: 31Cited Reference Count: 48},
	pages = {3931-3937},
	type = {Article},
	abstract = {{The direct reaction between ferrocene and an excess of molten 4-azabenzimidazole yielded amber-green crystals of polybis(4-azabenzimidazolato)iron(II), 1. Single crystal X-ray diffraction studies revealed tetrahedrally coordinated iron ions linked by single imidazolate bridges and forming a 3-D single diamond-like (diamondoid) extended lattice. Magnetization studies show the effects of antiferromagnetic exchange above a critical temperature},
	keywords = {CATIONS, COMPLEXES, CONSTRUCTION, coordination polymers, COPPER(I), CRYSTAL-STRUCTURES, LIGANDS, MAGNETIC-PROPERTIES, METAL PYRAZOLATE POLYMERS, NET},
	isbn = {1470-479X},
	url = {<Go to ISI>://000165330400026},
	author = {Rettig, S. J. and Sanchez, V. and Storr, A. and Thompson, R. C. and Trotter, J.}
}
@article {4541,
	title = {Chemistry of the Ag-2(dmb)(2)(2+) template (dmb=1,8-diisocyano-p-menthane). Preparation, characterization, and x-ray structures of the Ag-2(dmb)(2)Y-2 dimers (Y = NO3-, ClO4-, CH3CO2-) and the paramagnetic [Ag-4(dmb)(4)(TCNQ)(3)]TCNQ complex (TCNQ=7,7,8,8},
	journal = {Inorganic Chemistry},
	volume = {38},
	number = {6},
	year = {1999},
	note = {ISI Document Delivery No.: 180DKTimes Cited: 17Cited Reference Count: 43},
	month = {Mar},
	pages = {1253-1260},
	type = {Article},
	abstract = {{Direct reactions of the AgY salts with dmb (1,8-diisocyano-p-menthane) in a 1:1 stoichiometric amount generate the binuclear Ag-2(dmb)(2)Y-2 complexes. The X-ray crystallography establishes that the structure consists of two Ag+ atoms bridged by two dmb ligands forming a 20-membered ring and by two counteranions via one of the O-atoms, forming a four-membered ring (local symmetry D-2h) The Ag-I... Ag-I separations are 3.909(1) and 3.6831(8) Angstrom for Y = NO3- and CH3CO2-, respectively. Reactions of Ag-2(dmb)(2)Y-2 (Y = NO3-, ClO4-) with LiTCNQ lead to the paramagnetic tetranuclear species [Ag-4(dmb)(4)(TCNQ)(3)]TCNQ. The structure at 180 K consists of two Ag-2(dmb)(2)(2+) species (d(Ag ... Ag) = 4.113(1) Angstrom held together by three parallel TCNQ(-{\textquoteright})s, with Ag+... N=C distances ranging from 2.359(5) to 2.787(5) Angstrom. Two of the Ag+ atoms are tricoordinated, and the other two are tetracoordinated placed within in a centrosymmetric geometry. The three bridging TCNQ-{\textquoteright}s exhibit interplanar distances of 3.333(1) Angstrom, and the Ag-4 species are packed side-by-side with two adjacent TCNQ-{\textquoteright}s face-to-face (separation 3.372(1) Angstrom) forming an infinite pi-stacked chain TCNQ(-{\textquoteright})s. The TCNQ(-) counteranion also exhibits weak pi-contacts via the -CN groups with other counteranions. The magnetic susceptibilities, EPR spectra, and unit cell parameters have been measured as a function of temperature. The magnetic data are best explained by extended chains of anti Ferromagnetically coupled S = 3/2 and S = 1/2 centers for the [Ag-4(dmb)(4)-(TCNQ)(3)](+) and TCNQ(-) moieties, respectively. No hyperfine structure has been observed between 106 and 290 K, indicating the presence of rapid exchange in the paramagnetic system. Crystal data: Ag-2(dmb)(2)(NO3)(2), crystal system, orthorhombic, space group = C-cmb},
	keywords = {1, 7, 7{\textquoteright}, 8, 8-DIISOCYANO-P-MENTHANE, 8-TETRACYANOQUINODIMETHANE, 8{\textquoteright}-TETRACYANOQUINODIMETHANE, CRYSTAL-STRUCTURE, MAGNETIC-PROPERTIES, NICKEL(II), POLYMERS, SPECTROSCOPY, SYSTEMS, TCNQ},
	isbn = {0020-1669},
	url = {<Go to ISI>://000079370000030},
	author = {Fortin, D. and Drouin, M. and Harvey, P. D. and Herring, F. G. and Summers, D. A. and Thompson, R. C.}
}
@article {4541,
	title = {Chemistry of the Ag-2(dmb)(2)(2+) template (dmb=1,8-diisocyano-p-menthane). Preparation, characterization, and x-ray structures of the Ag-2(dmb)(2)Y-2 dimers (Y = NO3-, ClO4-, CH3CO2-) and the paramagnetic [Ag-4(dmb)(4)(TCNQ)(3)]TCNQ complex (TCNQ=7,7,8,8},
	journal = {Inorganic Chemistry},
	volume = {38},
	number = {6},
	year = {1999},
	note = {ISI Document Delivery No.: 180DKTimes Cited: 17Cited Reference Count: 43},
	month = {Mar},
	pages = {1253-1260},
	type = {Article},
	abstract = {{Direct reactions of the AgY salts with dmb (1,8-diisocyano-p-menthane) in a 1:1 stoichiometric amount generate the binuclear Ag-2(dmb)(2)Y-2 complexes. The X-ray crystallography establishes that the structure consists of two Ag+ atoms bridged by two dmb ligands forming a 20-membered ring and by two counteranions via one of the O-atoms, forming a four-membered ring (local symmetry D-2h) The Ag-I... Ag-I separations are 3.909(1) and 3.6831(8) Angstrom for Y = NO3- and CH3CO2-, respectively. Reactions of Ag-2(dmb)(2)Y-2 (Y = NO3-, ClO4-) with LiTCNQ lead to the paramagnetic tetranuclear species [Ag-4(dmb)(4)(TCNQ)(3)]TCNQ. The structure at 180 K consists of two Ag-2(dmb)(2)(2+) species (d(Ag ... Ag) = 4.113(1) Angstrom held together by three parallel TCNQ(-{\textquoteright})s, with Ag+... N=C distances ranging from 2.359(5) to 2.787(5) Angstrom. Two of the Ag+ atoms are tricoordinated, and the other two are tetracoordinated placed within in a centrosymmetric geometry. The three bridging TCNQ-{\textquoteright}s exhibit interplanar distances of 3.333(1) Angstrom, and the Ag-4 species are packed side-by-side with two adjacent TCNQ-{\textquoteright}s face-to-face (separation 3.372(1) Angstrom) forming an infinite pi-stacked chain TCNQ(-{\textquoteright})s. The TCNQ(-) counteranion also exhibits weak pi-contacts via the -CN groups with other counteranions. The magnetic susceptibilities, EPR spectra, and unit cell parameters have been measured as a function of temperature. The magnetic data are best explained by extended chains of anti Ferromagnetically coupled S = 3/2 and S = 1/2 centers for the [Ag-4(dmb)(4)-(TCNQ)(3)](+) and TCNQ(-) moieties, respectively. No hyperfine structure has been observed between 106 and 290 K, indicating the presence of rapid exchange in the paramagnetic system. Crystal data: Ag-2(dmb)(2)(NO3)(2), crystal system, orthorhombic, space group = C-cmb},
	keywords = {1, 7, 7{\textquoteright}, 8, 8-DIISOCYANO-P-MENTHANE, 8-TETRACYANOQUINODIMETHANE, 8{\textquoteright}-TETRACYANOQUINODIMETHANE, CRYSTAL-STRUCTURE, MAGNETIC-PROPERTIES, NICKEL(II), POLYMERS, SPECTROSCOPY, SYSTEMS, TCNQ},
	isbn = {0020-1669},
	url = {<Go to ISI>://000079370000030},
	author = {Fortin, D. and Drouin, M. and Harvey, P. D. and Herring, F. G. and Summers, D. A. and Thompson, R. C.}
}
@article {4641,
	title = {Iron(II) 2-methylimidazolate and copper(II) 1,2,4-triazolate complexes: systems exhibiting long-range ferromagnetic ordering at low temperatures},
	journal = {Canadian Journal of Chemistry-Revue Canadienne De Chimie},
	volume = {77},
	number = {4},
	year = {1999},
	note = {ISI Document Delivery No.: 204JXTimes Cited: 17Cited Reference Count: 27},
	month = {Apr},
	pages = {425-433},
	type = {Article},
	abstract = {{Crystals of [Fe(2-methylimidazolate)(2). 0.13(FeCp2)](x), 1, are orthorhombic},
	keywords = {1, 2, 2-methylimidazolate, 3, 4-triazolate, 5-DIMETHYLPYRAZOLATE, BR, canted spins, CH3, COMPLEXES, copper, CRYSTAL, ferromagnets, iron, LIGANDS, MAGNETIC-PROPERTIES, METAL PYRAZOLATE POLYMERS, METALLOCENES},
	isbn = {0008-4042},
	url = {<Go to ISI>://000080762100003},
	author = {Rettig, S. J. and Storr, A. and Summers, D. A. and Thompson, R. C. and Trotter, J.}
}
@article {4641,
	title = {Iron(II) 2-methylimidazolate and copper(II) 1,2,4-triazolate complexes: systems exhibiting long-range ferromagnetic ordering at low temperatures},
	journal = {Canadian Journal of Chemistry-Revue Canadienne De Chimie},
	volume = {77},
	number = {4},
	year = {1999},
	note = {ISI Document Delivery No.: 204JXTimes Cited: 17Cited Reference Count: 27},
	month = {Apr},
	pages = {425-433},
	type = {Article},
	abstract = {{Crystals of [Fe(2-methylimidazolate)(2). 0.13(FeCp2)](x), 1, are orthorhombic},
	keywords = {1, 2, 2-methylimidazolate, 3, 4-triazolate, 5-DIMETHYLPYRAZOLATE, BR, canted spins, CH3, COMPLEXES, copper, CRYSTAL, ferromagnets, iron, LIGANDS, MAGNETIC-PROPERTIES, METAL PYRAZOLATE POLYMERS, METALLOCENES},
	isbn = {0008-4042},
	url = {<Go to ISI>://000080762100003},
	author = {Rettig, S. J. and Storr, A. and Summers, D. A. and Thompson, R. C. and Trotter, J.}
}
@article {4641,
	title = {Iron(II) 2-methylimidazolate and copper(II) 1,2,4-triazolate complexes: systems exhibiting long-range ferromagnetic ordering at low temperatures},
	journal = {Canadian Journal of Chemistry-Revue Canadienne De Chimie},
	volume = {77},
	number = {4},
	year = {1999},
	note = {ISI Document Delivery No.: 204JXTimes Cited: 17Cited Reference Count: 27},
	month = {Apr},
	pages = {425-433},
	type = {Article},
	abstract = {{Crystals of [Fe(2-methylimidazolate)(2). 0.13(FeCp2)](x), 1, are orthorhombic},
	keywords = {1, 2, 2-methylimidazolate, 3, 4-triazolate, 5-DIMETHYLPYRAZOLATE, BR, canted spins, CH3, COMPLEXES, copper, CRYSTAL, ferromagnets, iron, LIGANDS, MAGNETIC-PROPERTIES, METAL PYRAZOLATE POLYMERS, METALLOCENES},
	isbn = {0008-4042},
	url = {<Go to ISI>://000080762100003},
	author = {Rettig, S. J. and Storr, A. and Summers, D. A. and Thompson, R. C. and Trotter, J.}
}
@article {4457,
	title = {Organometallic oxides: Preparation and properties of the clusters [(eta-C5Me5)V(mu(3)-O)](4) and [(eta-C5Me5)V](4)(mu-O)(6) by reductive aggregation of (eta-C5Me5)VCl2(O)},
	journal = {Organometallics},
	volume = {18},
	number = {5},
	year = {1999},
	note = {ISI Document Delivery No.: 174EYTimes Cited: 10Cited Reference Count: 56},
	month = {Mar},
	pages = {870-879},
	type = {Article},
	abstract = {Reduction of Cp*VCl2(O) (Cp* = eta-C5Me5) by the powerful reductants sodium, potassium, magnesium, or calcium or the amalgams of these metals gave a mixture of the black cubane-like cluster [Cp*V(mu(3)-O)](4) and the black-green adamantane-like cluster [Cp*V](4)(mu-O)(6). A concurrent coproduct of the formation of [Cp*V](4)(mu-O)(6) was dark purple [Cp*V(mu-Cl)(2)](3). The formation of [Cp*V]4(mu-O)(6) was favored in toluene, whereas [Cp*V(mu(3)-O)](4) was favored in tetrahydrofuran. The identity of the reductant did not influence the ratio of [Cp*V]4(mu-O)(6) to [Cp*V(mu(3)-O)](4) produced. A scheme for the reduction is proposed; the key intermediate is [Cp*VClO](2). The cluster [Cp*V(mu(3)-O)](4) was paramagnetic (mu(eff) = 2.35 mu(B) at 300 K), and [Cp*V]4(mu-O)(6) was diamagnetic. The syntheses of [Cp*VCl(O)](2)(mu-O) by treatment of Cp*VCl2(O) with Ag2CO3 and [Cp*VCl(mu-O)](4) (which is paramagnetic, mu(eff) = 4.51 mu(B) at 300 K) by reduction of Cp*VCl2(O) with mercury are reported.},
	keywords = {CRYSTAL-STRUCTURES, CUBANE, D-BLOCK, DERIVATIVES, ELECTRONIC-STRUCTURES, MAGNETIC-PROPERTIES, {COMPLEXES},
	isbn = {0276-7333},
	url = {<Go to ISI>://000079022200011},
	author = {Abernethy, C. D. and Bottomley, F. and Day, R. W. and Decken, A. and Summers, D. A. and Thompson, R. C.}
}
@article {4386,
	title = {Coordination complexes derived from 3,6-di(2-pyridyl)-1,4-dihydro-1,2,4,5-tetrazine (DPDHT). Synthesis and molecular structure of [(DPT)(GaMe2)2]},
	journal = {Canadian Journal of Chemistry-Revue Canadienne De Chimie},
	volume = {76},
	number = {12},
	year = {1998},
	note = {ISI Document Delivery No.: 180RKTimes Cited: 3Cited Reference Count: 25},
	month = {Dec},
	pages = {1800-1804},
	type = {Article},
	abstract = {{The facile reaction of 3,6-di(2-pyridyl)-1,4-dihydro-1,2,4,5-tetrazine (DPDHT) (1) with trimethylgallium has resulted in the formation of the purple crystalline product, [(DPT)(GaMe2)(2)] (2), via methane elimination. Crystals of [(DPT)(GaMe2)(2)] are orthorhombic, Pbca},
	keywords = {3, 5-DIMETHYLPYRAZOLATE, crystal structure, dipyridyldihydrotetrazine, MAGNETIC-PROPERTIES, METAL PYRAZOLATE POLYMERS, METALLOCENES, methylgallium},
	isbn = {0008-4042},
	url = {<Go to ISI>://000079398800003},
	author = {Preston, P. N. and Rettig, S. J. and Storr, A. and Trotter, J.}
}
@article {4386,
	title = {Coordination complexes derived from 3,6-di(2-pyridyl)-1,4-dihydro-1,2,4,5-tetrazine (DPDHT). Synthesis and molecular structure of [(DPT)(GaMe2)2]},
	journal = {Canadian Journal of Chemistry-Revue Canadienne De Chimie},
	volume = {76},
	number = {12},
	year = {1998},
	note = {ISI Document Delivery No.: 180RKTimes Cited: 3Cited Reference Count: 25},
	month = {Dec},
	pages = {1800-1804},
	type = {Article},
	abstract = {{The facile reaction of 3,6-di(2-pyridyl)-1,4-dihydro-1,2,4,5-tetrazine (DPDHT) (1) with trimethylgallium has resulted in the formation of the purple crystalline product, [(DPT)(GaMe2)(2)] (2), via methane elimination. Crystals of [(DPT)(GaMe2)(2)] are orthorhombic, Pbca},
	keywords = {3, 5-DIMETHYLPYRAZOLATE, crystal structure, dipyridyldihydrotetrazine, MAGNETIC-PROPERTIES, METAL PYRAZOLATE POLYMERS, METALLOCENES, methylgallium},
	isbn = {0008-4042},
	url = {<Go to ISI>://000079398800003},
	author = {Preston, P. N. and Rettig, S. J. and Storr, A. and Trotter, J.}
}
@article {4412,
	title = {Transition metal azolates from metallocenes. Part 3: Polymeric manganese(II) and nickel(II) pyrazolates; synthesis, characterization, and magnetochemistry},
	journal = {Canadian Journal of Chemistry-Revue Canadienne De Chimie},
	volume = {76},
	number = {8},
	year = {1998},
	note = {ISI Document Delivery No.: 143VNTimes Cited: 13Cited Reference Count: 37},
	month = {Aug},
	pages = {1130-1137},
	type = {Article},
	abstract = {Direct reactions of nickelocene and manganocene with molten pyrazoles in an inert atmosphere or under vacuum have led to the isolation of the following metal pyrazolate compounds: [Ni(4-Xpz)(2)](x) (where X = EI, CI and pz = pyrazolate); [M(4-Xdmpz)(2)](x) (where X = H, CH3, Cl, Br and M = Ni, Mn and dmpz = 3,5-dimethylpyazolate); and [Mn(4-Xpz)(2)(4-XpzH)](x) (where X = Cl, Br and pzH = pyrazole). On the basis of indirect evidence all compounds are considered to have extended chain structures with metal ions linked in chains by double bridging pyrazolates. The two [Ni(4-Xpz)2], compounds are diamagnetic while all others are paramagnetic. Variable temperature magnetic susceptibility studies on the paramagnetic compounds reveal antiferromagnetic coupling between neighbouring metal ions. Analysis of the magnetic data (Hamiltonian of the form II = -2J Sigma S-i S-j) yields values of the exchange coupling constant J of -14 to -17 cm(-1) for the [Ni(4-Xdmpz)(2)](x) compounds, -1.2 to -2.1 cm(-1) for the [Mn(4-Xdmpz)(2)](x) compounds, and -0.41 cm(-1) for the [Mn(4-Xpz)(2)(4-XpzH)](x) compounds.},
	keywords = {3, 5-DIMETHYLPYRAZOLATE, ANTIFERROMAGNETIC EXCHANGE, BR, CH3, COMPLEXES, CRYSTAL-STRUCTURE, LIGANDS, MAGNETIC-PROPERTIES, manganese, manganocene, NICKEL, nickelocene, pyrazolates, REACTIVITY},
	isbn = {0008-4042},
	url = {<Go to ISI>://000077277900003},
	author = {Storr, A. and Summers, D. A. and Thompson, R. C.}
}
@article {4412,
	title = {Transition metal azolates from metallocenes. Part 3: Polymeric manganese(II) and nickel(II) pyrazolates; synthesis, characterization, and magnetochemistry},
	journal = {Canadian Journal of Chemistry-Revue Canadienne De Chimie},
	volume = {76},
	number = {8},
	year = {1998},
	note = {ISI Document Delivery No.: 143VNTimes Cited: 13Cited Reference Count: 37},
	month = {Aug},
	pages = {1130-1137},
	type = {Article},
	abstract = {Direct reactions of nickelocene and manganocene with molten pyrazoles in an inert atmosphere or under vacuum have led to the isolation of the following metal pyrazolate compounds: [Ni(4-Xpz)(2)](x) (where X = EI, CI and pz = pyrazolate); [M(4-Xdmpz)(2)](x) (where X = H, CH3, Cl, Br and M = Ni, Mn and dmpz = 3,5-dimethylpyazolate); and [Mn(4-Xpz)(2)(4-XpzH)](x) (where X = Cl, Br and pzH = pyrazole). On the basis of indirect evidence all compounds are considered to have extended chain structures with metal ions linked in chains by double bridging pyrazolates. The two [Ni(4-Xpz)2], compounds are diamagnetic while all others are paramagnetic. Variable temperature magnetic susceptibility studies on the paramagnetic compounds reveal antiferromagnetic coupling between neighbouring metal ions. Analysis of the magnetic data (Hamiltonian of the form II = -2J Sigma S-i S-j) yields values of the exchange coupling constant J of -14 to -17 cm(-1) for the [Ni(4-Xdmpz)(2)](x) compounds, -1.2 to -2.1 cm(-1) for the [Mn(4-Xdmpz)(2)](x) compounds, and -0.41 cm(-1) for the [Mn(4-Xpz)(2)(4-XpzH)](x) compounds.},
	keywords = {3, 5-DIMETHYLPYRAZOLATE, ANTIFERROMAGNETIC EXCHANGE, BR, CH3, COMPLEXES, CRYSTAL-STRUCTURE, LIGANDS, MAGNETIC-PROPERTIES, manganese, manganocene, NICKEL, nickelocene, pyrazolates, REACTIVITY},
	isbn = {0008-4042},
	url = {<Go to ISI>://000077277900003},
	author = {Storr, A. and Summers, D. A. and Thompson, R. C.}
}
@article {3949,
	title = {Synthesis and characterization of the mixed valence Cu(I)/Cu(II) 3,5-bis(trifluoromethyl)-pyrazolate complex, [Cu(II)(2)Cu(I)(F(6)dmpz)(5)]},
	journal = {Canadian Journal of Chemistry-Revue Canadienne De Chimie},
	volume = {75},
	number = {5},
	year = {1997},
	note = {ISI Document Delivery No.: XF492Times Cited: 18Cited Reference Count: 17},
	month = {May},
	pages = {491-498},
	type = {Article},
	abstract = {{The reaction of molten 3,5-bis(trifluoromethyl)pyrazole (F(6)dmpzH) with copper metal shot under an atmosphere of dioxygen yields the green trimetallic mixed valence [Cu(II)(2)Cu(I)(F(6)dmpz)(5)]. Crystals of [Cu(II)(2)Cu(I)F(6)dmpz)(5)] are triclinic},
	keywords = {3, 5-bis(trifluoromethyl)pyrazolates, ANTIFERROMAGNETISM, copper, COPPER(II) COMPLEX, MAGNETIC-PROPERTIES, METAL PYRAZOLATE POLYMERS, RAY CRYSTAL-STRUCTURE, STRUCTURE, trimetallic, X-RAY},
	isbn = {0008-4042},
	url = {<Go to ISI>://A1997XF49200003},
	author = {Ehlert, M. K. and Storr, A. and Summers, D. A. and Thompson, R. C.}
}
@article {3949,
	title = {Synthesis and characterization of the mixed valence Cu(I)/Cu(II) 3,5-bis(trifluoromethyl)-pyrazolate complex, [Cu(II)(2)Cu(I)(F(6)dmpz)(5)]},
	journal = {Canadian Journal of Chemistry-Revue Canadienne De Chimie},
	volume = {75},
	number = {5},
	year = {1997},
	note = {ISI Document Delivery No.: XF492Times Cited: 18Cited Reference Count: 17},
	month = {May},
	pages = {491-498},
	type = {Article},
	abstract = {{The reaction of molten 3,5-bis(trifluoromethyl)pyrazole (F(6)dmpzH) with copper metal shot under an atmosphere of dioxygen yields the green trimetallic mixed valence [Cu(II)(2)Cu(I)(F(6)dmpz)(5)]. Crystals of [Cu(II)(2)Cu(I)F(6)dmpz)(5)] are triclinic},
	keywords = {3, 5-bis(trifluoromethyl)pyrazolates, ANTIFERROMAGNETISM, copper, COPPER(II) COMPLEX, MAGNETIC-PROPERTIES, METAL PYRAZOLATE POLYMERS, RAY CRYSTAL-STRUCTURE, STRUCTURE, trimetallic, X-RAY},
	isbn = {0008-4042},
	url = {<Go to ISI>://A1997XF49200003},
	author = {Ehlert, M. K. and Storr, A. and Summers, D. A. and Thompson, R. C.}
}
@article {4117,
	title = {Transition metal azolates from metallocenes .1. Dimetallic and trimetallic cyclopentadienyl nickel pyrazolates, synthesis and structural studies},
	journal = {Canadian Journal of Chemistry-Revue Canadienne De Chimie},
	volume = {75},
	number = {7},
	year = {1997},
	note = {ISI Document Delivery No.: XR886Times Cited: 10Cited Reference Count: 23},
	month = {Jul},
	pages = {949-958},
	type = {Article},
	abstract = {{The reactions of nickelocene with pyrazoles in benzene solution have resulted in the isolation of either dimeric compounds, [CpNi(mu-pz{\textquoteright})](2), (room temperature conditions) or trimetallic complexes, [CpNi(mu-pz {\textquoteright}{\textquoteright})(2)](2)Ni, (elevated temperature conditions). Both dimeric and trimetallic species were obtained as red crystalline materials and X-ray structural investigations are reported for representative samples of each type. Structural features are interpreted and compared with similar, previously reported, nickel pyrazolate structures. Crystals of [CpNi(3,5-diMepz)](2) (C20H24N4Ni2), 1, are orthorhombic},
	keywords = {3, 5-DIMETHYLPYRAZOLATE COMPLEXES, BR, CH3, CRYSTAL, crystal structures, CYCLOPENTADIENYL, MAGNETIC-PROPERTIES, MOLECULAR-STRUCTURES, NICKEL, nickelocene, POLYMERS, pyrazolates},
	isbn = {0008-4042},
	url = {<Go to ISI>://A1997XR88600004},
	author = {Rettig, S. J. and Storr, A. and Summers, D. A. and Thompson, R. C. and Trotter, J.}
}
@article {4117,
	title = {Transition metal azolates from metallocenes .1. Dimetallic and trimetallic cyclopentadienyl nickel pyrazolates, synthesis and structural studies},
	journal = {Canadian Journal of Chemistry-Revue Canadienne De Chimie},
	volume = {75},
	number = {7},
	year = {1997},
	note = {ISI Document Delivery No.: XR886Times Cited: 10Cited Reference Count: 23},
	month = {Jul},
	pages = {949-958},
	type = {Article},
	abstract = {{The reactions of nickelocene with pyrazoles in benzene solution have resulted in the isolation of either dimeric compounds, [CpNi(mu-pz{\textquoteright})](2), (room temperature conditions) or trimetallic complexes, [CpNi(mu-pz {\textquoteright}{\textquoteright})(2)](2)Ni, (elevated temperature conditions). Both dimeric and trimetallic species were obtained as red crystalline materials and X-ray structural investigations are reported for representative samples of each type. Structural features are interpreted and compared with similar, previously reported, nickel pyrazolate structures. Crystals of [CpNi(3,5-diMepz)](2) (C20H24N4Ni2), 1, are orthorhombic},
	keywords = {3, 5-DIMETHYLPYRAZOLATE COMPLEXES, BR, CH3, CRYSTAL, crystal structures, CYCLOPENTADIENYL, MAGNETIC-PROPERTIES, MOLECULAR-STRUCTURES, NICKEL, nickelocene, POLYMERS, pyrazolates},
	isbn = {0008-4042},
	url = {<Go to ISI>://A1997XR88600004},
	author = {Rettig, S. J. and Storr, A. and Summers, D. A. and Thompson, R. C. and Trotter, J.}
}
@article {4117,
	title = {Transition metal azolates from metallocenes .1. Dimetallic and trimetallic cyclopentadienyl nickel pyrazolates, synthesis and structural studies},
	journal = {Canadian Journal of Chemistry-Revue Canadienne De Chimie},
	volume = {75},
	number = {7},
	year = {1997},
	note = {ISI Document Delivery No.: XR886Times Cited: 10Cited Reference Count: 23},
	month = {Jul},
	pages = {949-958},
	type = {Article},
	abstract = {{The reactions of nickelocene with pyrazoles in benzene solution have resulted in the isolation of either dimeric compounds, [CpNi(mu-pz{\textquoteright})](2), (room temperature conditions) or trimetallic complexes, [CpNi(mu-pz {\textquoteright}{\textquoteright})(2)](2)Ni, (elevated temperature conditions). Both dimeric and trimetallic species were obtained as red crystalline materials and X-ray structural investigations are reported for representative samples of each type. Structural features are interpreted and compared with similar, previously reported, nickel pyrazolate structures. Crystals of [CpNi(3,5-diMepz)](2) (C20H24N4Ni2), 1, are orthorhombic},
	keywords = {3, 5-DIMETHYLPYRAZOLATE COMPLEXES, BR, CH3, CRYSTAL, crystal structures, CYCLOPENTADIENYL, MAGNETIC-PROPERTIES, MOLECULAR-STRUCTURES, NICKEL, nickelocene, POLYMERS, pyrazolates},
	isbn = {0008-4042},
	url = {<Go to ISI>://A1997XR88600004},
	author = {Rettig, S. J. and Storr, A. and Summers, D. A. and Thompson, R. C. and Trotter, J.}
}
@article {3842,
	title = {Solvolysis reactions in liquid antimony (V) fluoride. A convenient and versatile synthetic method},
	journal = {European Journal of Solid State and Inorganic Chemistry},
	volume = {33},
	number = {9},
	year = {1996},
	note = {ISI Document Delivery No.: VK527Times Cited: 9Cited Reference Count: 71},
	pages = {917-930},
	type = {Article},
	abstract = {{Solvolysis reactions of various fluorosulfates in liquid antimony (V) fluoride allow the synthesis of a wide range of fluoroantimonate (V) salts with main group, organometallic and transition metal cations. In the presence of carbon monoxide, CO, at pressures of 0.5 to 2.0 atmospheres a new group of homoleptic carbonyl cations of electronrich metals (Hg, Au, Pt, Pd, Ir, Ru, and Os) form with [Sb2F11](-) as anion. The salts show relatively high thermal stability (> 100 degrees C). The geometries of the cations [Au(CO)(2)](+), [Hg(CO)(2)](2+) (linear) and [M(CO)(4)](2+)},
	keywords = {CATIONS, CRYSTAL, FLUOROSULFATES, MAGNETIC-PROPERTIES, MAS NMR-SPECTRA, MOLECULAR-STRUCTURE, NOBLE-METALS, TRIS(FLUOROSULFATE), UNDECAFLUORODIANTIMONATE(V), VIBRATIONAL-SPECTRA},
	isbn = {0992-4361},
	url = {<Go to ISI>://A1996VK52700012},
	author = {Wang, C. and Hwang, G. and Siu, S. C. and Aubke, F. and Bley, B. and Bodenbinder, M. and Bach, C. and Willner, H.}
}
@article {2956,
	title = {CARBON-MONOXIDE AS A SIGMA-DONOR LIGAND IN COORDINATION CHEMISTRY},
	journal = {Coordination Chemistry Reviews},
	volume = {137},
	year = {1994},
	note = {ISI Document Delivery No.: PW818Times Cited: 84Cited Reference Count: 189},
	month = {Dec},
	pages = {483-524},
	type = {Review},
	abstract = {In addition to the numerous and varied examples of organometallic and coordination compounds where carbon monoxide functions as a pi-acceptor ligand, there is a small but select group of derivatives where the CO-metal bonding relies predominantly on a-bonding only. The metal derivatives, which include Pt(CO)(2)Cl-2 known since 1868, are formed by electron-rich metals (Pd, Pt, Ag and Au), in oxidation states +1 and +2, are cationic in nature, and are for the most part thermally stable. Their generation in strong protonic and Lewis acids (HSO3F, HSO3F-SbF5 and liquid SbF5) allows convenient synthesis. The predominance of sigma-bonding results in unusual spectroscopic properties, such as <(nu)over bar>CO stretching vibrations as high as 2280 cm(-1), relative to 2143 cm(-1) in free CO, and C-13 chemical shifts which are 180-130 ppm rather than 190-220 ppm for classical transition-metal carbonyls. Consequently two basic principles, the synergic bonding model and the rule of 18, fail for these complexes. Recent structural studies point to the importance of secondary OC...OS or OC...FSb contacts, which in place of pi-backdonation provide for a measure of charge compensation both in solution or in the solid state. This review concentrates on very recent (since 1990) developments in this field, which is expanding rapidly beyond the transition metals.},
	keywords = {FLUOROSULFATE DERIVATIVES, GOLD(III) FLUOROSULFATE, HIGHLY REDUCED ORGANOMETALLICS, LATE TRANSITION-ELEMENTS, MAGNETIC-PROPERTIES, MICROWAVE-SPECTRUM, MOLECULAR-STRUCTURE, NOBLE-METALS, THIONYL CHLORIDE, VIBRATIONAL-SPECTRA},
	isbn = {0010-8545},
	url = {<Go to ISI>://A1994PW81800013},
	author = {Aubke, F. and Wang, C.}
}
@article {2888,
	title = {COMPLEX POLYMERIC CATIONS OF COPPER(I) WITH GRAPHITE-RELATED AND DIAMOND-RELATED LATTICES - CRYSTAL-STRUCTURES OF POLY-TRIS(MU-2,5-DIMETHYLPYRAZINE)DICOPPER(I) HEXAFLUOROPHOSPHATE AND POLY-BIS(MU-2,5-DIMETHYLPYRAZINE)COPPER(I) HEXAFLUOROPHOSPHATE},
	journal = {Inorganic Chemistry},
	volume = {32},
	number = {9},
	year = {1993},
	note = {ISI Document Delivery No.: KZ801Times Cited: 94Cited Reference Count: 47},
	month = {Apr},
	pages = {1607-1611},
	type = {Article},
	abstract = {{Yellow crystals of composition [Cu2(2,5-me2pyz)3][PF6]2, 1, and orange-red ones of composition [Cu(2,5-me2-pyz)2] [PF6], 2, were obtained from the reaction Of Cu(ClO4)2-6H2O, KPF6, and 2,5-dimethylpyrazine in ethanol. Single-crystal X-ray diffraction studies on both are reported. Crystals of 1 are monoclinic},
	keywords = {cobalt(II), EXCHANGE, LIGANDS, MAGNETIC-PROPERTIES, MOLECULAR-STRUCTURE, NITROGEN-HETEROCYCLES, PERCHLORATE, Pyrazine, SPECTRUM, TRIFLUOROMETHANESULFONATE},
	isbn = {0020-1669},
	url = {<Go to ISI>://A1993KZ80100015},
	author = {Otieno, T. and Rettig, S. J. and Thompson, R. C. and Trotter, J.}
}
@article {2888,
	title = {COMPLEX POLYMERIC CATIONS OF COPPER(I) WITH GRAPHITE-RELATED AND DIAMOND-RELATED LATTICES - CRYSTAL-STRUCTURES OF POLY-TRIS(MU-2,5-DIMETHYLPYRAZINE)DICOPPER(I) HEXAFLUOROPHOSPHATE AND POLY-BIS(MU-2,5-DIMETHYLPYRAZINE)COPPER(I) HEXAFLUOROPHOSPHATE},
	journal = {Inorganic Chemistry},
	volume = {32},
	number = {9},
	year = {1993},
	note = {ISI Document Delivery No.: KZ801Times Cited: 94Cited Reference Count: 47},
	month = {Apr},
	pages = {1607-1611},
	type = {Article},
	abstract = {{Yellow crystals of composition [Cu2(2,5-me2pyz)3][PF6]2, 1, and orange-red ones of composition [Cu(2,5-me2-pyz)2] [PF6], 2, were obtained from the reaction Of Cu(ClO4)2-6H2O, KPF6, and 2,5-dimethylpyrazine in ethanol. Single-crystal X-ray diffraction studies on both are reported. Crystals of 1 are monoclinic},
	keywords = {cobalt(II), EXCHANGE, LIGANDS, MAGNETIC-PROPERTIES, MOLECULAR-STRUCTURE, NITROGEN-HETEROCYCLES, PERCHLORATE, Pyrazine, SPECTRUM, TRIFLUOROMETHANESULFONATE},
	isbn = {0020-1669},
	url = {<Go to ISI>://A1993KZ80100015},
	author = {Otieno, T. and Rettig, S. J. and Thompson, R. C. and Trotter, J.}
}
@article {2793,
	title = {{LOW-TEMPERATURE X-RAY-DIFFRACTION STUDIES ON [CU(4-XPZ)2]X LINEAR-CHAIN POLYMERS (WHERE X=CL, BR, CH3},
	journal = {Canadian Journal of Chemistry-Revue Canadienne De Chimie},
	volume = {71},
	number = {3},
	year = {1993},
	note = {ISI Document Delivery No.: KU982Times Cited: 20Cited Reference Count: 7},
	month = {Mar},
	pages = {331-334},
	type = {Article},
	abstract = {Room temperature and low-temperature (110-140 K) powder diffractograms have been obtained for the polymeric compounds [Cu(4-Xpz)2], (where X = H, CH3, Cl, and Br), and values of the unit cell parameters (orthorhombic, space group Ibam) a, b, and c have been obtained at both high and low temperatures. A single crystal X-ray diffraction study of the X = H compound at 116 K was completed and the results compared with a published study done at room temperature. The structures of these complexes involve extended chains of pyrazolate-bridged copper ions extending along the c crystallographic axis. The X-ray studies indicate little change in the c parameter with decreasing temperature and small but significant changes in the a or b parameters reflecting changes in interchain packing. This study permits some evaluation of how structural parameters are affected by these variations in interchain packing and how these variations may be affecting the magnitude of magnetic exchange in the compounds.},
	keywords = {MAGNETIC-PROPERTIES, METAL PYRAZOLATE POLYMERS},
	isbn = {0008-4042},
	url = {<Go to ISI>://A1993KU98200010},
	author = {Ehlert, M. K. and Storr, A. and Thompson, R. C. and Einstein, F. W. B. and Batchelor, R. J.}
}
@article {2793,
	title = {{LOW-TEMPERATURE X-RAY-DIFFRACTION STUDIES ON [CU(4-XPZ)2]X LINEAR-CHAIN POLYMERS (WHERE X=CL, BR, CH3},
	journal = {Canadian Journal of Chemistry-Revue Canadienne De Chimie},
	volume = {71},
	number = {3},
	year = {1993},
	note = {ISI Document Delivery No.: KU982Times Cited: 20Cited Reference Count: 7},
	month = {Mar},
	pages = {331-334},
	type = {Article},
	abstract = {Room temperature and low-temperature (110-140 K) powder diffractograms have been obtained for the polymeric compounds [Cu(4-Xpz)2], (where X = H, CH3, Cl, and Br), and values of the unit cell parameters (orthorhombic, space group Ibam) a, b, and c have been obtained at both high and low temperatures. A single crystal X-ray diffraction study of the X = H compound at 116 K was completed and the results compared with a published study done at room temperature. The structures of these complexes involve extended chains of pyrazolate-bridged copper ions extending along the c crystallographic axis. The X-ray studies indicate little change in the c parameter with decreasing temperature and small but significant changes in the a or b parameters reflecting changes in interchain packing. This study permits some evaluation of how structural parameters are affected by these variations in interchain packing and how these variations may be affecting the magnitude of magnetic exchange in the compounds.},
	keywords = {MAGNETIC-PROPERTIES, METAL PYRAZOLATE POLYMERS},
	isbn = {0008-4042},
	url = {<Go to ISI>://A1993KU98200010},
	author = {Ehlert, M. K. and Storr, A. and Thompson, R. C. and Einstein, F. W. B. and Batchelor, R. J.}
}
@article {2790,
	title = {OCTAMOLYBDENUM OXO-PYRAZOLATE CLUSTERS - SYNTHESES, CHARACTERIZATION, AND CRYSTAL AND MOLECULAR-STRUCTURES OF THE MO(V)/MO(VI) AND MO(VI) OCTAMOLYBDENUM CLUSTERS MO8(PZ)6O18(PZH)6 AND MO8(PZ)6O21(PZH)6},
	journal = {Inorganic Chemistry},
	volume = {32},
	number = {23},
	year = {1993},
	note = {ISI Document Delivery No.: MG613Times Cited: 20Cited Reference Count: 36},
	month = {Nov},
	pages = {5176-5182},
	type = {Article},
	abstract = {{Two octamolybdenum compounds, containing both bridging pyrazolate and terminal pyrazole ligands, have been prepared by the reaction of molten pyrazole with molybdenum oxides, and their structures have been determined by single-crystal X-ray diffraction. Crystals of Mo8(pz)6O18(pzH)6.2pzH (1;pzH=pyrazole, C3H4N2; pz = pyrazolate anion, C3H3N2) are monoclinic, space group C2/c, with a = 23.026(3) angstrom},
	keywords = {3, 5-DIMETHYLPYRAZOLATE, CATALYSIS, CHEMISTRY, COMPLEXES, HETEROPOLY, MAGNETIC-PROPERTIES, MOLYBDATES, MOLYBDENUM, OXYGEN, POLYMERS},
	isbn = {0020-1669},
	url = {<Go to ISI>://A1993MG61300039},
	author = {Ehlert, M. K. and Rettig, S. J. and Storr, A. and Thompson, R. C. and Trotter, J.}
}
@article {2790,
	title = {OCTAMOLYBDENUM OXO-PYRAZOLATE CLUSTERS - SYNTHESES, CHARACTERIZATION, AND CRYSTAL AND MOLECULAR-STRUCTURES OF THE MO(V)/MO(VI) AND MO(VI) OCTAMOLYBDENUM CLUSTERS MO8(PZ)6O18(PZH)6 AND MO8(PZ)6O21(PZH)6},
	journal = {Inorganic Chemistry},
	volume = {32},
	number = {23},
	year = {1993},
	note = {ISI Document Delivery No.: MG613Times Cited: 20Cited Reference Count: 36},
	month = {Nov},
	pages = {5176-5182},
	type = {Article},
	abstract = {{Two octamolybdenum compounds, containing both bridging pyrazolate and terminal pyrazole ligands, have been prepared by the reaction of molten pyrazole with molybdenum oxides, and their structures have been determined by single-crystal X-ray diffraction. Crystals of Mo8(pz)6O18(pzH)6.2pzH (1;pzH=pyrazole, C3H4N2; pz = pyrazolate anion, C3H3N2) are monoclinic, space group C2/c, with a = 23.026(3) angstrom},
	keywords = {3, 5-DIMETHYLPYRAZOLATE, CATALYSIS, CHEMISTRY, COMPLEXES, HETEROPOLY, MAGNETIC-PROPERTIES, MOLYBDATES, MOLYBDENUM, OXYGEN, POLYMERS},
	isbn = {0020-1669},
	url = {<Go to ISI>://A1993MG61300039},
	author = {Ehlert, M. K. and Rettig, S. J. and Storr, A. and Thompson, R. C. and Trotter, J.}
}
@article {2790,
	title = {OCTAMOLYBDENUM OXO-PYRAZOLATE CLUSTERS - SYNTHESES, CHARACTERIZATION, AND CRYSTAL AND MOLECULAR-STRUCTURES OF THE MO(V)/MO(VI) AND MO(VI) OCTAMOLYBDENUM CLUSTERS MO8(PZ)6O18(PZH)6 AND MO8(PZ)6O21(PZH)6},
	journal = {Inorganic Chemistry},
	volume = {32},
	number = {23},
	year = {1993},
	note = {ISI Document Delivery No.: MG613Times Cited: 20Cited Reference Count: 36},
	month = {Nov},
	pages = {5176-5182},
	type = {Article},
	abstract = {{Two octamolybdenum compounds, containing both bridging pyrazolate and terminal pyrazole ligands, have been prepared by the reaction of molten pyrazole with molybdenum oxides, and their structures have been determined by single-crystal X-ray diffraction. Crystals of Mo8(pz)6O18(pzH)6.2pzH (1;pzH=pyrazole, C3H4N2; pz = pyrazolate anion, C3H3N2) are monoclinic, space group C2/c, with a = 23.026(3) angstrom},
	keywords = {3, 5-DIMETHYLPYRAZOLATE, CATALYSIS, CHEMISTRY, COMPLEXES, HETEROPOLY, MAGNETIC-PROPERTIES, MOLYBDATES, MOLYBDENUM, OXYGEN, POLYMERS},
	isbn = {0020-1669},
	url = {<Go to ISI>://A1993MG61300039},
	author = {Ehlert, M. K. and Rettig, S. J. and Storr, A. and Thompson, R. C. and Trotter, J.}
}
@article {7225,
	title = {{METAL PYRAZOLATE POLYMERS .3. SYNTHESIS AND STUDY OF CU(I) AND CU(II) COMPLEXES OF 4-XDMPZ (WHERE X = H, CL, BR, I, AND CH3 FOR CU(I) AND X = H, CL, BR, AND CH3 FOR CU(II)},
	journal = {Canadian Journal of Chemistry-Revue Canadienne De Chimie},
	volume = {70},
	number = {4},
	year = {1992},
	note = {ISI Document Delivery No.: JH895Times Cited: 33Cited Reference Count: 24},
	month = {Apr},
	pages = {1121-1128},
	type = {Article},
	abstract = {The copper(I) complexes [Cu(4-Xdmpz)]3 (where X = H, Cl, Br, I and CH3; dmpz = 3,5-dimethylpyrazolate) and the copper(II) complexes [Cu(4-Xdmpz)2]x have been synthesized and characterized. Qualitative solubility, infrared spectroscopic, and differential scanning calorimetric studies are reported for all complexes. Mass spectra support trimeric formulations for the copper(I) complexes. Scanning electron micrographs and powder X-ray diffractograms have been recorded for the copper(II) compounds. Electronic and EPR spectroscopic studies as well as magnetic susceptibility studies from 2 to 300 K are also reported for the copper(II) compounds, which are proposed to have polymeric chain structures. The magnetic data reveal strong antiferromagnetic interactions in all four of the copper(II) compounds. The data have been analysed employing an isotropic Heisenberg model for antiferromagnetic coupling in extended chain polymers. Values of the exchange coupling constant, J, are determined as -58, -61, -66, and -66 cm-1 for the X = H, CH3, Cl, and Br complexes respectively. The X = Cl compound exhibits an abrupt decrease in magnetic susceptibility below 40 K and possible causes of this anomalous behaviour are discussed.},
	keywords = {MAGNETIC-PROPERTIES, RAY CRYSTAL-STRUCTURE, RING},
	isbn = {0008-4042},
	url = {<Go to ISI>://A1992JH89500015},
	author = {Ehlert, M. K. and Storr, A. and Thompson, R. C.}
}
@article {7225,
	title = {{METAL PYRAZOLATE POLYMERS .3. SYNTHESIS AND STUDY OF CU(I) AND CU(II) COMPLEXES OF 4-XDMPZ (WHERE X = H, CL, BR, I, AND CH3 FOR CU(I) AND X = H, CL, BR, AND CH3 FOR CU(II)},
	journal = {Canadian Journal of Chemistry-Revue Canadienne De Chimie},
	volume = {70},
	number = {4},
	year = {1992},
	note = {ISI Document Delivery No.: JH895Times Cited: 33Cited Reference Count: 24},
	month = {Apr},
	pages = {1121-1128},
	type = {Article},
	abstract = {The copper(I) complexes [Cu(4-Xdmpz)]3 (where X = H, Cl, Br, I and CH3; dmpz = 3,5-dimethylpyrazolate) and the copper(II) complexes [Cu(4-Xdmpz)2]x have been synthesized and characterized. Qualitative solubility, infrared spectroscopic, and differential scanning calorimetric studies are reported for all complexes. Mass spectra support trimeric formulations for the copper(I) complexes. Scanning electron micrographs and powder X-ray diffractograms have been recorded for the copper(II) compounds. Electronic and EPR spectroscopic studies as well as magnetic susceptibility studies from 2 to 300 K are also reported for the copper(II) compounds, which are proposed to have polymeric chain structures. The magnetic data reveal strong antiferromagnetic interactions in all four of the copper(II) compounds. The data have been analysed employing an isotropic Heisenberg model for antiferromagnetic coupling in extended chain polymers. Values of the exchange coupling constant, J, are determined as -58, -61, -66, and -66 cm-1 for the X = H, CH3, Cl, and Br complexes respectively. The X = Cl compound exhibits an abrupt decrease in magnetic susceptibility below 40 K and possible causes of this anomalous behaviour are discussed.},
	keywords = {MAGNETIC-PROPERTIES, RAY CRYSTAL-STRUCTURE, RING},
	isbn = {0008-4042},
	url = {<Go to ISI>://A1992JH89500015},
	author = {Ehlert, M. K. and Storr, A. and Thompson, R. C.}
}
